Hybrid Biomimetic Materials from Silica/Carbonate Biomorphs

被引:10
作者
Opel, Julian [1 ,2 ]
Unglaube, Niklas [1 ]
Woerner, Melissa [1 ]
Kellermeier, Matthias [3 ]
Coelfen, Helmut [1 ]
Garcia-Ruiz, Juan-Manuel [2 ]
机构
[1] Univ Konstanz, Phys Chem, Univ Str 10, D-78457 Constance, Germany
[2] Inst Andaluz Ciencias Tierra CSIC UGR, Lab Estudios Cristalog, Ave Palmeras 4, E-18100 Granada, Spain
[3] BASF SE, Mat Phys, RAA OS B007,Carl Bosch Str 38, D-67056 Ludwigshafen, Germany
来源
CRYSTALS | 2019年 / 9卷 / 03期
基金
欧洲研究理事会;
关键词
biomorphs; barium carbonate; silica; PCDA; pyrrole; GROWTH-BEHAVIOR; SELF-ORGANIZATION; CARBONATE; MORPHOLOGY; THERMOCHROMISM; MORPHOGENESIS;
D O I
10.3390/cryst9030157
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The formation of a polymer protection layer around fragile mineral architectures ensures that structures stay intact even after treatments that would normally destroy them going along with a total loss of textural information. Here we present a strategy to preserve the shape of silica-carbonate biomorphs with polymers. This method converts non-hybrid inorganic-inorganic composite materials such a silica/carbonate biomorphs into hybrid organic/carbonate composite materials similar to biominerals.
引用
收藏
页数:8
相关论文
共 50 条
[21]   The Role of Calcium and Strontium as the Most Dominant Elements during Combinations of Different Alkaline Earth Metals in the Synthesis of Crystalline Silica-Carbonate Biomorphs [J].
Cuellar-Cruz, Mayra ;
Moreno, Abel .
CRYSTALS, 2019, 9 (08)
[22]   Rapid synthesis of polymer-silica hybrid nanofibers by biomimetic mineralization [J].
Patel, Pritesh A. ;
Eckart, Jessica ;
Advincula, Maria C. ;
Goldberg, A. Jon ;
Mather, Patrick T. .
POLYMER, 2009, 50 (05) :1214-1222
[23]   Systematic characterization of polycrystalline silica-carbonate helices [J].
Nakouzi, Elias ;
Knoll, Pamela ;
Hendrix, Kenzie B. ;
Steinbock, Oliver .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (33) :23044-23052
[24]   PREPARATION OF POLYMERIC MICROSPHERE-SILICA HYBRID MATERIALS BY ALKOXIDE PROCESS [J].
YAMAZAKI, S ;
HATTORI, S .
KOBUNSHI RONBUNSHU, 1993, 50 (05) :375-382
[25]   Mesoporous Hybrid Materials by Simultaneous Pseudomorphic Transformation and Functionalization of Silica Microspheres [J].
Reber, Michael J. ;
Bruehwiler, Dominik .
PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION, 2015, 32 (02) :243-250
[26]   Synthesis of fullerene-silica hybrid materials [J].
Angelini, Giancarlo ;
Ursini, Ornella ;
Cataldo, Franco .
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2010, 284 (01) :179-187
[27]   Synthesis of fullerene-silica hybrid materials [J].
Giancarlo Angelini ;
Ornella Ursini ;
Franco Cataldo .
Journal of Radioanalytical and Nuclear Chemistry, 2010, 284 :179-187
[28]   Silica/lignosulfonate hybrid materials: Preparation and characterization [J].
Klapiszewski, Lukasz ;
Zdarta, Jakub ;
Szatkowski, Tomasz ;
Wysokowski, Marcin ;
Nowacka, Magdalena ;
Szwarc-Rzepka, Karolina ;
Bartczak, Przemysaw ;
Siwinska-Stefanska, Katarzyna ;
Ehrlich, Hermann ;
Jesionowski, Teofil .
CENTRAL EUROPEAN JOURNAL OF CHEMISTRY, 2014, 12 (06) :719-735
[29]   Formation of Crystalline Silica-Carbonate Biomorphs of Alkaline Earth Metals (Ca, Ba, Sr) from Ambient to Low Temperatures: Chemical Implications during the Primitive Earth's Life [J].
Cuellar-Cruz, Mayra ;
Schneider, Dieter K. ;
Stojanoff, Vivian ;
Islas, Selene R. ;
Sanchez-Puig, Nuria ;
Arreguin-Espinosa, Roberto ;
Miguel Delgado, Jose ;
Moreno, Abel .
CRYSTAL GROWTH & DESIGN, 2020, 20 (02) :1186-1195
[30]   The effect of glycine on the growth of calcium carbonate in alkaline silica gel [J].
Gan, Xiong ;
He, Kunhuan ;
Qian, Baosong ;
Deng, Qin ;
Lu, Laixian ;
Wang, Yun .
JOURNAL OF CRYSTAL GROWTH, 2017, 458 :60-65