Simple synthesis of porous carbon sheet by reduction reaction of in-situ formed carbon dioxide for supercapacitor application

被引:9
作者
Wang, Jian [1 ]
Chen, Shengrui [2 ]
Deng, Heming [4 ]
Tang, Shun [2 ]
Cao, Yuan-Cheng [3 ]
Liang, Jiyuan [2 ]
机构
[1] State Grid Xinjiang Co Ltd, Elect Power Res Inst, Urumqi 830011, Xinjiang, Peoples R China
[2] Jianghan Univ, Sch Chem & Environm Engn, Minist Educ, Key Lab Optoelect Chem Mat & Devices, Wuhan 430056, Hubei, Peoples R China
[3] Huazhong Univ Sci & Technol, Sch Elect & Elect Engn, Wuhan 430074, Hubei, Peoples R China
[4] State Grid Elect Power Res Inst, Wuhan 430074, Hubei, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon materials; Porous materials; Carbon dioxide; NaBH4; Supercapacitor; ELECTRODE MATERIAL; ACTIVATED CARBON; PERFORMANCE; TEMPLATE; BIOMASS; SHELL;
D O I
10.1016/j.rinp.2019.01.035
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Porous carbon sheet (PCS) was prepared by reduction reaction between NaBH4 and the in-situ formed CO2 gas from the thermal-decomposition of NaHCO3 under inert atmosphere. During this preparation process, NaHCO3 also could be used as the activation agent and increases the specific surface area of carbon materials. The obtained PCS has a specific surface area of 828 m(2)/g. At a current density of 0.5 A/g, the specific capacitance of the PCS electrode is 201 F/g. Furthermore, the PCS electrode exhibits excellent rate capability (80% capacitance retention at 15 A/g) and superior cycling stability. These results suggest a facile and environmental benign method to prepare economical and high quality porous carbon sheet materials for energy storage applications.
引用
收藏
页码:1340 / 1343
页数:4
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