Ruthenium-catalyzed selective and efficient oxygenation of hydrocarbons with water as an oxygen source

被引：128

作者：

Hirai, Yuichirou ^{[1
,2
]}

Kojima, Takahiko ^{[1
,2
]}

Mizutani, Yasuhisa ^{[3
]}

Shiota, Yoshihito ^{[4
]}

Yoshizawa, Kazunari ^{[4
]}

Fukuzumi, Shunichi ^{[1
,2
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Mat & Life Sci, Suita, Osaka 5650871, Japan

[2] SORST, JST, Suita, Osaka 5650871, Japan

[3] Osaka Univ, Grad Sch Sci, Toyonaka, Osaka 5600043, Japan

[4] Kyushu Univ, Inst Mat Chem & Engn, Nishi Ku, Fukuoka 8190395, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 31期

关键词：

cerium; homogeneous catalysis; oxidation; redox chemistry; ruthenium;

D O I：

10.1002/anie.200801170

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Water is not only the solvent but also the sole oxygen source in the smooth and efficient oxidation of organic compounds catalyzed by a RuII-pyridylamine-aqua complex with CeIV as the oxidant. An intermediate-spin RuIV-oxo complex is formed as the reactive species (see scheme; Sub = substrate). This catalytic system is durable and able to gain high turnover numbers for various substrates. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5772 / 5776

页数：5

共 30 条

[1] The catalytic pathway of horseradish peroxidase at high resolution [J].

Berglund, GI ;

Carlsson, GH ;

Smith, AT ;

Szöke, H ;

Henriksen, A ;

Hajdu, J .

NATURE, 2002, 417 (6887) :463-468

[2] NOVEL RUTHENIUM OXO COMPLEXES OF SATURATED MACROCYCLES WITH NITROGEN AND OXYGEN DONORS AND X-RAY CRYSTAL-STRUCTURE OF TRANS-[RUIV(L)O(H2O)][CLO4]2 [J].

CHE, CM ;

TANG, WT ;

WONG, WT ;

LAI, TF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (25) :9048-9056

[3] A NOVEL MONOOXORUTHENIUM(V) COMPLEX CONTAINING A POLYDENTATE PYRIDYL AMINE LIGAND - SYNTHESES, REACTIVITIES, AND X-RAY CRYSTAL-STRUCTURE OF [RUIII(N4O)(H2O)](CLO4)2 [J].

CHE, CM ;

YAM, VWW ;

MAK, TCW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (06) :2284-2291

[4] SYNTHESIS, REACTIVITIES, AND STRUCTURAL STUDIES ON HIGH-VALENT RUTHENIUM OXO COMPLEXES - RUTHENIUM(IV), RUTHENIUM(V), AND RUTHENIUM(VI) OXO COMPLEXES OF TERTIARY AMINE LIGANDS [J].

CHE, CM ;

LAI, TF ;

WONG, KY .

INORGANIC CHEMISTRY, 1987, 26 (14) :2289-2299

[5]

de Montellano P.R. Ortiz., 1995, CYTOCHROME P450 STRU

[6] REDOX PROPERTIES AND LIGAND LOSS CHEMISTRY IN AQUA HYDROXO OXO COMPLEXES DERIVED FROM CIS-[(BPY)2RU2(OH2)2]2+ AND TRANS-[(BPY)2RUII(OH2)2]2+ [J].

DOBSON, JC ;

MEYER, TJ .

INORGANIC CHEMISTRY, 1988, 27 (19) :3283-3291

[7] WATER-SOLUBLE HEXADENTATE SCHIFF-BASE LIGANDS AS SEQUESTRATING AGENTS FOR IRON(III) AND GALLIUM(III) [J].

EVANS, DF ;

JAKUBOVIC, DA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (12) :2927-2933

[8]

FROLAND WA, 1992, J BIOL CHEM, V267, P17588

[9] STRUCTURE AND REDOX PROPERTIES OF THE WATER-OXIDATION CATALYST [(BPY)2(OH2)RUORU(OH2)(BPY)2]4+ [J].

GILBERT, JA ;

EGGLESTON, DS ;

MURPHY, WR ;

GESELOWITZ, DA ;

GERSTEN, SW ;

HODGSON, DJ ;

MEYER, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :3855-3864

[10] CATALYTIC-OXIDATION OF HYDROCARBONS WITH O2 OR H2O2 USING A STERICALLY HINDERED RUTHENIUM COMPLEX [J].

GOLDSTEIN, AS ;

BEER, RH ;

DRAGO, RS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (06) :2424-2429

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