Investigation of the Inhibitive Effect of Octanesulfonic Acid-Zinc Ion System on Corrosion of Carbon Steel

被引:16
作者
Anbarasi, C. Mary [2 ]
Rajendran, Susai [1 ,3 ]
机构
[1] GTN Arts Coll, PG & Res Dept Chem, Corros Res Ctr, Dindigul 624005, India
[2] Jayaraj Annapackiam Coll Women, PG Dept Chem, Periyakulam, India
[3] RVS Sch Engn & Technol, Dept Chem, Dindigul, India
关键词
Carbon steel; Corrosion inhibition; FT-IR; Octanesulfonic acid; SEM; CO2; CORROSION; MILD-STEEL; WATER; PERFORMANCE; COPPER; IRON; NACL; OIL;
D O I
10.1080/00986445.2012.672498
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Inhibition of corrosion of carbon steel in dam water by octanesulfonic acid as its sodium salt (SOS) in the absence and presence of a bivalent cation zinc ion (Zn2+) has been investigated using weight loss, potentiodynamic polarization, AC impedance spectra, Fourier transform-infrared spectroscopy (FT-IR), fluorescence spectra, scanning electron microscopy (SEM), and energy dispersive X-ray detection (EDAX) measurements. The formulation consisting of 250 ppm of SOS and 30 ppm of Zn2+ offers 88% inhibition efficiency (IE) to carbon steel. The influence of sodium potassium tartrate on the IE of the SOS-Zn2+ system has been evaluated. Polarization study reveals that SOS-Zn2+ system controls the anodic reaction predominantly. AC impedance spectra reveal that a protective film is formed on the metal surface. The nature of the protective film formed on the metal surface has been analyzed by FT-IR spectra, SEM, and EDAX analysis.
引用
收藏
页码:1596 / 1609
页数:14
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