Passive direct alcohol fuel cell using methanol and 2-propanol mixture as a fuel

被引:11
作者
Munjewar, Seema S. [1 ]
Thombre, Shashikant B. [1 ]
Patil, Awanikumar P. [2 ]
机构
[1] Visvesvaraya Natl Inst Technol, Dept Mech Engn, Nagpur 440010, Maharashtra, India
[2] Visvesvaraya Natl Inst Technol, Dept Met & Mat Engn, Nagpur 440010, Maharashtra, India
关键词
DMFC; DAFC; Methanol; 2-Propanol; ACR; PERFORMANCE; ELECTROOXIDATION; DMFC; OXIDATION; ETHANOL; ALLOY; ANODE;
D O I
10.1007/s11581-018-2627-y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This article examines the effect of addition of small concentration of 2-propanol on the direct methanol fuel cell (DMFC) in passive mode. The different concentration ratio of the alcohol mixture (methanol +2-propanol) is used with constant methanol concentration and by varying 2-propanol concentration in the solution. The new passive direct alcohol fuel cell (DAFC) performance with different alcohol concentration ratio (ACR) has been compared with conventional passive DMFC. The cyclic voltammetry (CV) test, polarization test, and electrochemical impedance spectroscopy (EIS) are carried out to complete the different aspect of the cell performance. The result shows that DAFC with different ACR yields the better performance than the conventional passive DMFC. In this study, the passive DAFC at 1:0.5 ACR shows the optimum cell performance.
引用
收藏
页码:2231 / 2241
页数:11
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