Enantiopure Water-Soluble [Fe4L6] Cages: Host-Guest Chemistry and Catalytic Activity

被引：196

作者：

Bolliger, Jeanne L. ^{[1
]}

Belenguer, Ana M. ^{[1
]}

Nitschke, Jonathan R. ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 31期

基金：

英国工程与自然科学研究理事会; 瑞士国家科学基金会; 欧洲研究理事会;

关键词：

chirality; host-guest systems; organophosphates; self-assembly; supramolecular chemistry; COORDINATION CAGE; AQUEOUS-MEDIUM; ORGANIC CAGES; DIELS-ALDER; RECOGNITION; CAPSULES; DETOXIFICATION; ENCAPSULATION; HYDROLYSIS; POLYHEDRA;

D O I：

10.1002/anie.201302136

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Inside information: The new enantiopure cage molecule ΔΔΔ Δ-Fe4L6 (and its enantiomer, ΛΛ ΛΛ-Fe4L6) was prepared by subcomponent self-assembly. It binds a range of organic guests (A, see scheme) in its cavity and distinguishes between the enantiomers of a chiral organic guest. Host ΔΔΔΔ-Fe4L6 is also a catalyst for the hydrolysis (giving B and C) of the neurotoxic organophosphate dichlorvos. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7958 / 7962

页数：5

共 50 条

[1] "Induced Fit" in Chiral Recognition: Epimerization upon Dimerization in the Hierarchical Self-Assembly of Helicate-type Titanium(IV) Complexes [J].

Albrecht, Markus ;

Isaak, Elisabeth ;

Baumert, Miriam ;

Gossen, Verena ;

Raabe, Gerhard ;

Froehlich, Roland .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (12) :2850-2853

[2]

Bolliger J.L., 2007, ANGEW CHEMIE, V119, P6634

[3] Short, facile, and high-yielding synthesis of extremely efficient pincer-type suzuki catalysts bearing aminoiphosphine substituents [J].

Bolliger, Jeanne L. ;

Blacque, Olivier ;

Frech, Christian M. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (34) :6514-6517

[4] The 1,3-Diaminobenzene-Derived Aminophosphine Palladium Pincer Complex {C6H3[NHP(piperidinyl)2]2Pd(Cl)} - A Highly Active Suzuki-Miyaura Catalyst with Excellent Functional Group Tolerance [J].

Bolliger, Jeanne L. ;

Frech, Christian M. .

ADVANCED SYNTHESIS & CATALYSIS, 2010, 352 (06) :1075-1080

[5] Enantioselective Catalysis of the Aza-Cope Rearrangement by a Chiral Supramolecular Assembly [J].

Brown, Casey J. ;

Bergman, Robert G. ;

Raymond, Kenneth N. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (48) :17530-17531

[6] Luminescent, Enantiopure, Phenylatopyridine Iridium-Based Coordination Capsules [J].

Chepelin, Oleg ;

Ujma, Jakub ;

Wu, Xiaohua ;

Slawin, Alexandra M. Z. ;

Pitak, Mateusz B. ;

Coles, Simon J. ;

Michel, Julien ;

Jones, Anita C. ;

Barran, Perdita E. ;

Lusby, Paul J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (47) :19334-19337

[7] Constitutionally selective amplification of multicomponent 84-membered macrocyclic hosts for (-)-cytidine•H+ [J].

Chung, Mee-Kyung ;

Severin, Kay ;

Lee, Stephen J. ;

Waters, Marcey L. ;

Gagne, Michel R. .

CHEMICAL SCIENCE, 2011, 2 (04) :744-747

[8] Encapsulation versus Aggregation of Metal-Organic Cages Controlled by Guest Size Variation [J].

Clever, Guido H. ;

Kawamura, Wataru ;

Shionoya, Mitsuhiko .

INORGANIC CHEMISTRY, 2011, 50 (11) :4689-4691

[9] Biomimicking, metal-chelating and surface-imprinted polymers for the degradation of pesticides [J].

Erdem, Murat ;

Say, Ridvan ;

Ersoz, Arzu ;

Denizli, Adil ;

Turk, Hayrettin .

REACTIVE & FUNCTIONAL POLYMERS, 2010, 70 (04) :238-243

[10] Guest-controlled self-sorting in assemblies driven by the hydrophobic effect [J].

Gan, Haiying ;

Gibb, Bruce C. .

CHEMICAL COMMUNICATIONS, 2012, 48 (11) :1656-1658

← 1 2 3 4 5 →