Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Aminoarylation of Alkenes

被引：429
|
作者：
Sahoo, Basudev [1 ]
Hopkinson, Matthew N. [1 ]
Glorius, Frank [1 ]
机构：
[1] Univ Munster, NRW Grad Sch Chem, Inst Organ Chem, D-48149 Munster, Germany
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 15期
基金：
欧洲研究理事会;
关键词：
ARYL DIAZONIUM SALTS; C-H ARYLATION; CROSS-COUPLING REACTIONS; UNACTIVATED ALKENES; DUAL CATALYSIS; METAL-FREE; PALLADIUM; ALDEHYDES; PHOTOCATALYSIS; OXYARYLATION;
D O I：
10.1021/ja400311h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A room-temperature intramolecular oxy- and aminoarylation of alkenes with aryldiazonium salts has been developed using a novel gold and photoredox dual-catalytic system. The compatibility of these two catalytic modes has been established for the first time and demonstrates the potential of this system as a method to expand the scope of nucleophilic addition reactions to carbon-carbon multiple bonds.
引用
收藏
页码：5505 / 5508
页数：4
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