Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Aminoarylation of Alkenes

被引：437

作者：

Sahoo, Basudev ^{[1
]}

Hopkinson, Matthew N. ^{[1
]}

Glorius, Frank ^{[1
]}

机构：

[1] Univ Munster, NRW Grad Sch Chem, Inst Organ Chem, D-48149 Munster, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 15期

基金：

欧洲研究理事会;

关键词：

ARYL DIAZONIUM SALTS; C-H ARYLATION; CROSS-COUPLING REACTIONS; UNACTIVATED ALKENES; DUAL CATALYSIS; METAL-FREE; PALLADIUM; ALDEHYDES; PHOTOCATALYSIS; OXYARYLATION;

D O I：

10.1021/ja400311h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A room-temperature intramolecular oxy- and aminoarylation of alkenes with aryldiazonium salts has been developed using a novel gold and photoredox dual-catalytic system. The compatibility of these two catalytic modes has been established for the first time and demonstrates the potential of this system as a method to expand the scope of nucleophilic addition reactions to carbon-carbon multiple bonds.

引用

页码：5505 / 5508

页数：4

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