Catalytic oxidation of benzene over ruthenium-cobalt bimetallic catalysts and study of its mechanism

被引：127

作者：

Liu, Xiaolong ^{[1
]}

Zeng, Junlin ^{[1
]}

Shi, Wenbo ^{[1
,2
]}

Wang, Jian ^{[1
]}

Zhu, Tingyu ^{[1
,3
]}

Chen, Yunfa ^{[1
]}

机构：

[1] Chinese Acad Sci, Beijing Engn Res Ctr Proc Pollut Control, Inst Proc Engn, Natl Engn Lab Hydrometallurg Cleaner Prod Technol, Beijing 100190, Peoples R China

[2] China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China

[3] Chinese Acad Sci, Ctr Excellence Reg Atmospher Environm, Inst Urban Environm, Xiamen 361021, Peoples R China

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2017年 / 7卷 / 01期

基金：

北京市自然科学基金;

关键词：

VOLATILE ORGANIC-COMPOUNDS; PREFERENTIAL OXIDATION; V2O5/TIO2; CATALYSTS; LOW-TEMPERATURES; OXYGEN MOBILITY; OXIDE CATALYSTS; CARBON-MONOXIDE; GOLD CATALYSTS; ETHYL-ACETATE; DOPED CERIA;

D O I：

10.1039/c6cy02141g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this work, ruthenium-based bimetallic catalysts of the formula Ru-5M/TiO2 (M = Mn, Co, Ce, Cu, Fe) were prepared and evaluated in benzene oxidation, and Ru-Co-5/TiO2 exhibited the lowest complete oxidation temperature (220 degrees C), demonstrating Co3O4 as the best dopant. The influence of the Ru and Co contents on the catalytic activity was also studied, and 1 wt% Ru and 5 wt% Co3O4 were confirmed. Water vapor showed an inhibition effect on benzene oxidation at 210 degrees C, whereas the catalytic efficiency was barely influenced at a higher temperature (230 degrees C). STEM analyses revealed that Ru-Co bimetallic species showed similar distributions on the catalytic surface. Based on the correlation of the catalytic results with various characterization techniques, the synergistic effect between Ru and Co was well demonstrated, and a four-step transformation in the oxidation process was concluded. Besides, systematic in situ FTIR studies for benzene oxidation over Ru/TiO2, Co/TiO2, and Ru-5Co/TiO2 were conducted and compared, and many organic intermediates were observed in the in situ FTIR spectra. Accordingly, the reaction mechanism for benzene oxidation over the Ru-Co bimetallic catalyst was proposed.

引用

页码：213 / 221

页数：9

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