Polyurethane-based cation exchange composite membranes: Preparation, characterization and its application in development of ion-selective electrode for detection of copper(II)

被引：9

作者：

Baig, Umair ^{[1
,2
]}

Khan, Asif Ali ^{[1
]}

机构：

[1] Aligarh Muslim Univ, Fac Engn & Technol, Dept Appl Chem, Analyt & Polymer Res Lab, Aligarh 202002, Uttar Pradesh, India

[2] King Fahd Univ Petr & Minerals, Ctr Excellence Sci Res Collaborat MIT, Dhahran 31261, Saudi Arabia

来源：

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2015年 / 29卷

关键词：

Polymer; Composite membranes; Cation exchanger; Cu(II) selective electrode;

D O I：

10.1016/j.jiec.2014.12.045

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polyurethane-cerium(IV) phosphate composite cation exchange membranes were prepared by casting method in different stoicheometric ratios of polyurethane and cerium(IV) phosphate. structure and morphology of the prepared membranes were ascertained by FTIR, SEM, TGA and membrane having composition 1:2 (PU: cerium(IV) phosphate) shows best results for capacity, water content, porosity, thickness and swelling. The Cu(II) selective electrode was using this membrane for the determination of Cu(II) in solutions. The accuracy of the procedure has tested on drinking water samples spiked with known amounts of Cu(II) and results were those generated by Atomic Absorption Spectrophotometer. (C) 2015 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

引用

页码：392 / 399

页数：8

共 28 条

[1] Copper(II)-selective electrode based on dithioacetal
Abbaspour, A
Kamyabi, MA
[J]. ANALYTICA CHIMICA ACTA, 2002, 455 (02) : 225 - 231
[2] A comparative study of theoretical, electrochemical and ionic transport through PVC based Cu3(PO4)2 and polystyrene supported Ni3(PO4)2 composite ion exchange porous membranes
Arsalan, Mohd
Khan, Mohammad Mujahid Ali
Rafiuddin
[J]. DESALINATION, 2013, 318 : 97 - 106
[3] Synthesis of New [1,2,4] Triazolo[3,4-b][1,3,4] thiadiazines and Study of Their Anti-Candidal and Cytotoxic Activities
Bhat, Mashooq Ahmad
Khan, Abdul Arif
Khan, Shahanavaj
Al-Dhfyan, Abdullah
[J]. JOURNAL OF CHEMISTRY, 2014, 2014
[4] Mixed matrix membranes (MMMs) comprising organic polymers with dispersed inorganic fillers for gas separation
Chung, Tai-Shung
Jiang, Lan Ying
Li, Yi
Kulprathipanja, Santi
[J]. PROGRESS IN POLYMER SCIENCE, 2007, 32 (04) : 483 - 507
[5] Faust S., 1987, ADSORPTION PROCESSES
[6] Guilbault G.G., 1969, ION SEL ELECTRODE RE, V1, P139
[7] Fabrication and electrochemical characterization of PVC based electrodialysis heterogeneous ion exchange membranes filled with Fe3O4 nanoparticles
Hosseini, S. M.
Askari, M.
Koranian, P.
Madaeni, S. S.
Moghadassi, A. R.
[J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2014, 20 (04) : 2510 - 2520
[8] SOLID MEMBRANES OF COPPER HEXACYANOFERRATE(III) AS THALLIUM(I) SENSITIVE ELECTRODE
JAIN, AK
SINGH, RP
BALA, C
[J]. ANALYTICAL LETTERS PART A-CHEMICAL ANALYSIS, 1982, 15 (19): : 1557 - 1563
[9] Polyacrylonitrile-based organic-inorganic composite anion-exchange membranes: Preparation, characterization and its application in making ion-selective membrane electrode for determination of As(V)
Khan, A. A.
Baig, Umair
[J]. DESALINATION, 2012, 289 : 21 - 26
[10] Khan A.A., 2011, AM J CHEM, V157, P122

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