Heavier group 2 element-catalysed hydroamination of isocyanates

被引：48

作者：

Barrett, Anthony G. M. ^{[1
]}

Boorman, Tanya C. ^{[2
]}

Crimmin, Mark R. ^{[1
]}

Hill, Michael S. ^{[2
]}

Kociok-Kohn, Gabriele ^{[2
]}

Procopiou, Panayiotis A. ^{[3
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[2] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[3] GlaxoSmithKline Med Res Ctr, Stevenage SG1 2NY, Herts, England

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 41期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b809649j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The heteroleptic calcium amides [{ArNC(Me)CHC(Me)NAr}Ca(NR(2))(THF)] (Ar = 2,6-di-iso-propylphenyl, R = SiMe(3), Ph) and the homoleptic heavier alkaline earth amides, [M{N(SiMe(3))(2)}(2)] (M = Ca, Sr and Ba) are reported as pre-catalysts for the hydroamination of isocyanates.

引用

页码：5206 / 5208

页数：3

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