Heavier group 2 element-catalysed hydroamination of isocyanates

被引：48
作者：
Barrett, Anthony G. M. [1 ]
Boorman, Tanya C. [2 ]
Crimmin, Mark R. [1 ]
Hill, Michael S. [2 ]
Kociok-Kohn, Gabriele [2 ]
Procopiou, Panayiotis A. [3 ]
机构：
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
[2] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
[3] GlaxoSmithKline Med Res Ctr, Stevenage SG1 2NY, Herts, England
来源：
CHEMICAL COMMUNICATIONS | 2008年 / 41期
基金：
英国工程与自然科学研究理事会;
关键词：
D O I：
10.1039/b809649j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The heteroleptic calcium amides [{ArNC(Me)CHC(Me)NAr}Ca(NR(2))(THF)] (Ar = 2,6-di-iso-propylphenyl, R = SiMe(3), Ph) and the homoleptic heavier alkaline earth amides, [M{N(SiMe(3))(2)}(2)] (M = Ca, Sr and Ba) are reported as pre-catalysts for the hydroamination of isocyanates.
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收藏
页码：5206 / 5208
页数：3
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