Dynamic Zn-based metal-organic framework: stepwise adsorption, hysteretic desorption and selective carbon dioxide uptake

被引：59

作者：

Liu, Bo ^{[1
]}

Li, Yuanpu ^{[1
]}

Hou, Lei ^{[1
]}

Yang, Guoping ^{[1
]}

Wang, Yao-Yu ^{[1
]}

Shi, Qi-Zhen ^{[1
]}

机构：

[1] NW Univ Xian, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Shaanxi Key Lab Physicoinorgan Chem,Coll Chem & M, Xian 710069, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2013年 / 1卷 / 22期

关键词：

POROUS COORDINATION POLYMERS; GAS-ADSORPTION; SORPTION PROPERTIES; CO2; PORES; HYDROGEN; CAPTURE; CRYSTALS; CHANNEL; SENSORS;

D O I：

10.1039/c3ta10918f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new porous metal-organic framework based on paddle-wheel Zn-2 units and an unsymmetrical pyridyl dicarboxylate, contains a 3D intersecting pore system with uncommon stepwise adsorption and hysteretic desorption behavior for N-2, CO2 and H-2 gases at low temperature, and shows high selectivity for CO2 over N-2 at ambient temperature.

引用

页码：6535 / 6538

页数：4

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