Multiphase ceramics based on powders synthesized from sodium pyrophosphate and soluble calcium salts using mechanical activation

被引：5

作者：

Safronova, T. V. ^{[1
]}

Secheiko, P. A. ^{[1
]}

Putlyaev, V. I. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Moscow, Russia

来源：

GLASS AND CERAMICS | 2012年 / 69卷 / 7-8期

关键词：

mechanical activation; calcium pyrophosphate; double sodium calcium pyrophosphate - cana-phite CaNa2P2O7 center dot 4H(2)O; double sodium calcium orthophosphate - renanite NaCaPO4; sodium pyrophosphate; porous ceramics; CRYSTAL-FORMATION;

D O I：

10.1007/s10717-012-9462-9

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A multiphase ceramics has been obtained from calcium phosphate powders synthesized by mechanical activation from sodium pyrophosphate and soluble calcium salts (acetate, nitrate, chloride). After synthesis from sodium pyrophosphate and calcium acetate or calcium nitrate the powders comprised a mixture of double calcium-sodium phosphate, unreacted calcium salt and reaction byproduct (NaNO3 or NaCH3COO). After synthesis from sodium pyrophosphate and calcium chloride the powders comprised a mixture of amorphous calcium phosphate and byproduct NaCl. After heat-treatment the phase composition of the samples depended on the firing temperature and the composition of the initial powders. After firing Ca2P2O7, Na2CaP2O7, NaCaPO4 and Ca-3(PO4)(2) were present in the samples.

引用

页码：276 / 282

页数：7

共 15 条

[1]

Cave Matthew R., 2010, THESIS U BIRMINGHAM

[2]

CHENG PT, 1980, J RHEUMATOL, V7, P609

[3] Wet or dry mechanochemical synthesis of calcium phosphates? Influence of the water content on DCPD-CaO reaction kinetics [J].

El Briak-BenAbdeslam, H. ;

Ginebra, M. P. ;

Vert, M. ;

Boudeville, P. .

ACTA BIOMATERIALIA, 2008, 4 (02) :378-386

[4]

ERIKSSON G, 1979, ANAL CHIM ACTA-COMP, V3, P375

[5] Mechanical activation and cement formation of β-tricalcium phosphate [J].

Gbureck, U ;

Grolms, O ;

Barralet, JE ;

Grover, LM ;

Thull, R .

BIOMATERIALS, 2003, 24 (23) :4123-4131

[6]

INGRI N, 1968, TALANTA, V15, pR6

[7]

Korneichuk S. A., 2008, PERSPEKT MAT, P91

[8]

Lurie Yu. Yu., 1989, Handbook of Analytical Chemistry

[9]

PRITZKER KPH, 1981, J RHEUMATOL, V8, P451

[10]

Puigdomenech I., MEDUSA MAKE EQUILIBR

← 1 2 →