A microwave study of the hetero-chiral dimer of butan-2-ol

被引：72

作者：

King, AK ^{[1
]}

Howard, BJ ^{[1
]}

机构：

[1] Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

来源：

CHEMICAL PHYSICS LETTERS | 2001年 / 348卷 / 3-4期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0009-2614(01)01121-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first observation of a rotationally resolved spectrum for a dimeric complex of chiral molecules is reported. The complex in question is a hydrogen-bonded dimer of butan-2-ol and is shown to be hetero-chiral in composition. The rotational constants and components of the dipole moment agree well with the predictions of an ab initio study, the initial results of which are also reported. The ability of chiral species to form diastereoisomeric hetero- and homo-chiral complexes is thus given strong support. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：343 / 349

页数：7

共 50 条

[41] Excess volumes of (hexane or cyclohexane plus propan-2-ol or butan-2-ol) at the temperatures (288.15 and 298.15) K [J].

Morrone, SR ;

Francesconi, AZ .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1996, 28 (09) :935-940

[42] THERMODYNAMIC PROPERTIES OF ORGANIC OXYGEN COMPOUNDS .28. VAPOUR PRESSURE OF (+)-BUTAN-2-OL [J].

AMBROSE, D ;

SPRAKE, CHS .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (09) :1261-&

[43] Absolute configuration of (2S)-4-(4-hydroxyphenyl)butan-2-ol [J].

Yousuf, S. ;

Musharraf, S. G. ;

Khan, I. ;

Samiullah ;

Fun, Hoong-Kun .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 :O952-U1205

[44] THE ASYMMETRIC ACETYLATION OF (+/-)-BUTAN-2-OL BY PARA-NITROPHENYL ACETATE AND ALPHA-CHYMOTRYPSIN [J].

ISAACS, NS ;

NIEMANN, C .

BIOCHIMICA ET BIOPHYSICA ACTA, 1960, 44 (01) :196-197

[45] CATALYSIS BY HYDROGEN HALIDES IN GAS PHASE .6. BUTAN-2-OL AND HYDROGEN BROMIDE [J].

FAILES, RL ;

STIMSON, VR .

JOURNAL OF THE CHEMICAL SOCIETY, 1962, (FEB) :653-&

[46] INFRARED STUDIES OF THE EFFECT OF PREADSORBED PYRIDINE ON THE OXIDATION OF BUTAN-2-OL ADSORBED ON TIO2 [J].

NAKAJIMA, T ;

MIYATA, H ;

KUBOKAWA, Y .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1983, 79 :2559-2568

[47] Interfacial solvent structure in butan-1-ol, butan-2-ol and 2-methylpropan-1-ol at Au and Ag electrodes from surface enhanced Raman scattering and capacitance measurements [J].

Pemberton, JE ;

Joa, SL ;

Shen, AJ ;

Woelfel, KJ .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (20) :3683-3691

[48] Characterization of active sites on AgHf2(PO4)3 in butan-2-ol conversion [J].

Brik, Y ;

Kacimi, M ;

Bozon-Verduraz, F ;

Ziyad, M .

MICROPOROUS AND MESOPOROUS MATERIALS, 2001, 43 (01) :103-112

[49] Isobaric vapor-liquid equilibria for methyl esters plus butan-2-ol at different pressures [J].

Ortega, J ;

Hernandez, P .

FLUID PHASE EQUILIBRIA, 1996, 118 (02) :249-270

[50] CO2 LASER-INDUCED DECOMPOSITION OF PROPAN-2-OL, BUTAN-2-OL, PENTAN-2-OL, PENTAN-3-OL, AND HEXAN-2-OL [J].

BISHOP, M ;

HOLBROOK, KA ;

OLDERSHAW, GA ;

DYER, PE .

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1994, 26 (01) :201-210

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