First Born differential cross-sections for electronic excitation in the helium atom

被引:54
作者
Cann, NM
Thakkar, AJ [1 ]
机构
[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada
[2] Univ New Brunswick, Dept Chem, Fredericton, NB E3B 6E2, Canada
关键词
helium; electron impact differential cross-sections; elastic and inelastic scattering; first Born approximation; generalized oscillator strengths;
D O I
10.1016/S0368-2048(02)00016-6
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Generalized oscillator strengths for transitions from the ground state of the helium atom to the n(1)S, n(1)P, and n(1)D states with n < 7 are obtained from explicitly correlated wave functions. These results are used to calculate, within the first Born approximation (FBA), elastic and inelastic differential cross-sections for scattering of electrons with impact energies between 100 and 1500 eV. Detailed comparisons between FBA and measured cross-sections are presented. At small angles, the FBA is accurate over a large range of impact energies for the optically allowed transitions to the n(1)P states. The FBA reaches a comparable level of accuracy for optically forbidden transitions only at higher impact energies. The FBA is significantly in error for elastic scattering in the forward direction even at 1500-eV impact energy. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:143 / 159
页数:17
相关论文
共 45 条
[1]   ACCURATE FIRST BORN APPROXIMATION CROSS SECTIONS FOR EXCITATION OF HELIUM BY FAST ELECTRONS [J].
BELL, KL ;
KENNEDY, DJ ;
KINGSTON, AE .
JOURNAL OF PHYSICS PART B ATOMIC AND MOLECULAR PHYSICS, 1969, 2 (01) :26-&
[2]   RATIONAL-FUNCTION FITS TO THE NONRESONANT ELASTIC DIFFERENTIAL CROSS-SECTIONS (DCS) FOR E + HE COLLISIONS, 0-DEGREES-180-DEGREES, 0.1 TO 1000 EV [J].
BOESTEN, L ;
TANAKA, H .
ATOMIC DATA AND NUCLEAR DATA TABLES, 1992, 52 (01) :25-42
[3]   Separation of angles in the two-electron problem [J].
Breit, G .
PHYSICAL REVIEW, 1930, 35 (06) :0569-0578
[4]  
BROWN RT, 1970, PHYS REV A, V1, P1343
[5]   ELASTIC ELECTRON-ATOM SCATTERING AT INTERMEDIATE ENERGIES [J].
BYRON, FW ;
JOACHAIN, CJ .
PHYSICAL REVIEW A, 1973, 8 (03) :1267-1282
[6]   ELASTIC-SCATTERING OF FAST ELECTRONS BY HELIUM [J].
BYRON, FW ;
JOACHAIN, CJ .
PHYSICAL REVIEW A, 1973, 8 (06) :3266-3269
[7]   ELASTIC-SCATTERING OF ELECTRONS AND POSITRONS BY COMPLEX ATOMS AT INTERMEDIATE ENERGIES [J].
BYRON, FW ;
JOACHAIN, CJ .
PHYSICAL REVIEW A, 1977, 15 (01) :128-146
[8]   CHARGE AND INTRACULE DENSITIES IN SINGLY EXCITED HELIUM-LIKE IONS [J].
CANN, NM ;
BOYD, RJ ;
THAKKAR, AJ .
JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (09) :7132-7139
[9]   OSCILLATOR-STRENGTHS FOR S-P AND P-D TRANSITIONS IN HELIUM-LIKE IONS [J].
CANN, NM ;
THAKKAR, AJ .
PHYSICAL REVIEW A, 1992, 46 (09) :5397-5405
[10]  
CANN NM, 1993, INT J QUANTUM CHEM, P33