Investigation of voltammetric behavior of 4-nitroaniline based on electrodeposition of silver particles onto graphite electrode

Electrochemical modification of carbon-paste electrode (CPEs) by silver particles and its applicability for electroanalytical determination of 4-nitroaniline (4-NA) were reported in this study. Electrochemical surface modification was performed by cyclic voltammetry within the range from 600 to -400mV in solution containing 0.5mmolL(-1) AgNO3 dissolved in 0.1molL(-1) of KNO3 at the scan rate of 10mVs(-1) by applying 1.5 cycles (six segments). Silver particles deposited onto surface of carbon-paste electrode (Ag-CPE) were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The proposed catalyst exhibits remarkably an electro-catalytic performance toward 4-nitroaniline reduction. The catalytic peak current obtained by differential pulse voltammetry (DPV) was linearly dependent on the 4-NA concentration over the range of 8.0x10(-8) to 1.0x10(-4)molL(-1) with a detection limit of 4.18x10(-8)molL(-1). The proposed sensor was successfully applied for 4-nitroaniline determination in drinking water samples.