Kinetics and mechanism of cumene peroxide cleavage in the presence of 2-mercaptobenzimidazole

被引：0

作者：

Nikolaevsky, AM ^{[1
]}

Filippenko, TA ^{[1
]}

Myroshnychenko, TM ^{[1
]}

Marshtupa, VP ^{[1
]}

机构：

[1] DONETSK STATE UNIV,UA-340055 DONETSK,UKRAINE

来源：

TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA | 1997年 / 33卷 / 01期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The 2-mercaptobenzimidazole cumene hydroperoxide interaction has been shown to be accompanied by radical formation. This causes 2-mercaptobenzimidazole promotion of isopropylbenzene and ethylbenzene autooxidation. At the same time, 2-mercaptobenzimidazole is a weak inhibitor in the processes of low-temperature promoted oxidation of alkylbenzenes.

引用

页码：44 / 48

页数：5

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