Kinetics and mechanism of cumene peroxide cleavage in the presence of 2-mercaptobenzimidazole

被引：0
|
作者：
Nikolaevsky, AM [1 ]
Filippenko, TA [1 ]
Myroshnychenko, TM [1 ]
Marshtupa, VP [1 ]
机构：
[1] DONETSK STATE UNIV,UA-340055 DONETSK,UKRAINE
来源：
TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA | 1997年 / 33卷 / 01期
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The 2-mercaptobenzimidazole cumene hydroperoxide interaction has been shown to be accompanied by radical formation. This causes 2-mercaptobenzimidazole promotion of isopropylbenzene and ethylbenzene autooxidation. At the same time, 2-mercaptobenzimidazole is a weak inhibitor in the processes of low-temperature promoted oxidation of alkylbenzenes.
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页码：44 / 48
页数：5
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