Luminescence and energy transfer in Lu3Al5O12 scintillators co-doped with Ce3+ and Pr3+

被引:53
作者
Ogieglo, J. M. [1 ]
Zych, A. [1 ]
Juestel, T. [2 ]
Meijerink, A. [1 ]
Ronda, C. R. [1 ,3 ,4 ]
机构
[1] Univ Utrecht, CMI, Debye Inst Nanomat Sci, NL-3508 TA Utrecht, Netherlands
[2] Univ Appl Sci Munster, D-48565 Steinfurt, Germany
[3] Philips Res Europe Eindhoven, NL-5656 AE Eindhoven, Netherlands
[4] Zhejiang Univ, Ctr Opt & Electromagnet Res, Hangzhou 310058, Zhejiang, Peoples R China
关键词
Computed tomography; Scintillator; Energy transfer; Garnet; Zero-phonon line; Self Trapped Exciton; INORGANIC SCINTILLATORS; TEMPERATURE-DEPENDENCE; SPECTROSCOPY; DEFECTS; GAP;
D O I
10.1016/j.optmat.2012.08.010
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Lu3Al5O12:Ce3+ (LuAG:Ce) is a scintillator with a fast response time. The light yield is lower than theoretically expected and to increase the light yield co-doping with Pr3+ is investigated. To better understand the energy flow to the Ce3+ ion, first low temperature emission and excitation spectra of Pr3+ doped LuAG were investigated, allowing the accurate determination of the zero-phonon lines for the 5d states of Pr3+ in LuAG and the temperature dependent energy transfer from the Self Trapped Exciton to Pr3+. In addition VUV excitation and soft X-ray excited emission spectra of the co-doped LuAG:Ce,Pr were studied. The results show that energy transfer from Pr3+ to Ce3+ occurs but it is followed by back transfer to the 4f states of Pr3+. (c) 2012 Published by Elsevier B.V.
引用
收藏
页码:322 / 331
页数:10
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