Crystalline WO3 nanoparticles for highly improved electrochromic applications

被引:549
作者
Lee, SH [1 ]
Deshpande, R [1 ]
Parilla, PA [1 ]
Jones, KM [1 ]
To, B [1 ]
Mahan, AH [1 ]
Dillon, AC [1 ]
机构
[1] Natl Renewable Energy Lab, Div Basic Sci, Golden, CO 80401 USA
关键词
D O I
10.1002/adma.200501953
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electrochromic materials change optical properties (darken/lighten) in the presence of a small electric potential difference, making them suitable for many applications. By fabricating porous films from crystalline WO3 nanoparticles (see figure), this state-of-the-art technology has been profoundly advanced. Significantly enhanced durability, increased charge insertion, and better kinetics have been demonstrated with an economical deposition process suitable for large-area applications.
引用
收藏
页码:763 / +
页数:5
相关论文
共 27 条
  • [1] The first truly all-polymer electrochromic devices
    Argun, AA
    Cirpan, A
    Reynolds, JR
    [J]. ADVANCED MATERIALS, 2003, 15 (16) : 1338 - +
  • [2] Controlled electrodeposition of nanoparticulate tungsten oxide
    Baeck, SH
    Jaramillo, T
    Stucky, GD
    McFarland, EW
    [J]. NANO LETTERS, 2002, 2 (08) : 831 - 834
  • [3] Photoelectrochromic windows and displays
    Bechinger, C
    Ferrer, S
    Zaban, A
    Sprague, J
    Gregg, BA
    [J]. NATURE, 1996, 383 (6601) : 608 - 610
  • [4] Comparison between electrochromic and photochromic coloration efficiency of tungsten oxide thin films
    Bechinger, C
    Burdis, MS
    Zhang, JG
    [J]. SOLID STATE COMMUNICATIONS, 1997, 101 (10) : 753 - 756
  • [5] Chandrasekhar P., 2002, ADV FUNCT MATER, V14, P3118
  • [6] OPTICAL AND PHOTOELECTRIC PROPERTIES AND COLOR CENTERS IN THIN-FILMS OF TUNGSTEN OXIDE
    DEB, SK
    [J]. PHILOSOPHICAL MAGAZINE, 1973, 27 (04): : 801 - 822
  • [7] Hot-wire chemical vapor synthesis for a variety of nano-materials with novel applications
    Dillon, AC
    Mahan, AH
    Deshpande, R
    Alleman, JL
    Blackburn, JL
    Parillia, PA
    Heben, MJ
    Engtrakul, C
    Gilbert, KEH
    Jones, KM
    To, R
    Lee, SH
    Lehman, JH
    [J]. THIN SOLID FILMS, 2006, 501 (1-2) : 216 - 220
  • [8] Continuous hot wire chemical vapor deposition of high-density carbon multiwall nanotubes
    Dillon, AC
    Mahan, AH
    Parilla, PA
    Alleman, JL
    Heben, MJ
    Jones, KM
    Gilbert, KEH
    [J]. NANO LETTERS, 2003, 3 (10) : 1425 - 1429
  • [9] FAUGHNAN BW, 1980, TOP APPL PHYS, V40, P181
  • [10] Plastic electrochromic devices: Electrochemical characterization and device properties of a phenothiazine-phenylquinoline donor-acceptor polymer
    Fungo, F
    Jenekhe, SA
    Bard, AJ
    [J]. CHEMISTRY OF MATERIALS, 2003, 15 (06) : 1264 - 1272