Preparation and characterization of crednerite glass-ceramics in the MnO • CuO • SiO2 system

Nanoscale crednerite (CuMnO2) was prepared in the system MnO center dot CuO center dot SiO2, using glass ceramics technique for the first time. Based on obtained data from differential thermal analysis (DTA), the prepared samples were heat-treated at 700 and 800 degrees C for 2 h. The presence of crystalline phases after and before heat treatment was investigated by X-ray diffraction analysis. Crystallization of crednerite (CuMnO2), manganese silicate (Mn2SiO4) and traces of cuprite (Cu2O) and cristobalite (SiO2) phases were recognized. Transmission electron microscopy showed nanoscale crystals in the range 5-10 nm. The prepared glass-ceramics showed ferrimagnetic properties with wide range coercivity from 53 to 2217 Hci and magnetization saturation from 0.21708 to 1.2 emu/g. From IR reflection data; the reflection intensity of the light is high in the range of orange-red color and violet -blue colors and low in the range of green color. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.