Axial chirality control by 2,4-pentanediol or its analogue as a simple chiral linking bridge. Highly diastereodifferentiating homocoupling of a 1-lithio-2-naphthyl ether

被引：51

作者：

Sugimura, T

Yamada, H

Inoue, S

Tai, A

机构：

[1] Faculty of Science, Himeji Institute of Technology

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 04期

关键词：

D O I：

10.1016/S0957-4166(97)00022-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Diastereodifferentiating oxidative homocoupling of 1-lithio-2-naphthyl ether linked by optically active 2,4-pentanediol or 1,3-diphenyl-1,3-propanediol gave 2,2'-binaphthyl ether of over 99% diastereomeric excess. By elimination of the chiral auxiliary from the product, enantiomerically pure binaphthol was obtained in good yield. (C) 1997 Elsevier Science Ltd.

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页码：649 / 655

页数：7

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