Chemical precipitation of struvite: Nutrients recovery in conic fluidized bed reactor using a low-cost industrial magnesia compound

被引:2
作者
Castro, Samuel Rodrigues [1 ]
Crutchik, Dafne [1 ]
Garrido, Juan Manuel [2 ]
Lange, Lisete Celina [3 ]
机构
[1] Univ Santiago de Compostela, Santiago De Compostela, Galicia, Spain
[2] Univ Santiago de Compostela, Dept Engn Quim, Santiago De Compostela, Galicia, Spain
[3] Univ Fed Minas Gerais, Dept Engn Sanitaria & Ambiental, Belo Horizonte, MG, Brazil
关键词
nutrients recovery; chemical precipitation; struvite; industrial magnesia compound; low-cost reagent; conic fluidized bed reactor; WASTE-WATER; PILOT-SCALE; AMMONIUM; REMOVAL; CRYSTALLIZATION; HYDRATION;
D O I
10.1590/S1413-41522015020000133827
中图分类号
TV21 [水资源调查与水利规划];
学科分类号
081501 ;
摘要
The physico-chemical process of struvite precipitation is a technique that demonstrates a high potential in nutrients recovery from different kinds of wastewaters. This study aimed to evaluate the use of a low cost industrial compound with high magnesia content as alternative reagent source of magnesium ions and alkalinity required for precipitation. It was a strategy to turn the process economically viable and reduce the chemical costs. Mg(OH)(2) slurries were obtained and evaluated regarding the nutrients recovery from a synthetic wastewater rich in NH4+-N and PO43--P and the quality of the generated crystals with the identification of the mineral of interest - the struvite. The experiment was performed in laboratory scale using a conic fluidized bed reactor in a semi-continuous operation. The proper pH control (8.0-8.5) by the automated addition of Mg(OH)(2) slurry allowed considerable PO43--P removal equal to 93.5%. The recovered solids from the process showed purity of approximately 84% of struvite.
引用
收藏
页码:259 / 268
页数:10
相关论文
共 26 条
[21]  
MYERSON A. S., 2002, HDB IND CRYSTALLIZAT, P13
[22]   A pilot-scale study of struvite precipitation in a stirred tank reactor: Conditions influencing the process [J].
Pastor, L. ;
Mangin, D. ;
Barat, R. ;
Seco, A. .
BIORESOURCE TECHNOLOGY, 2008, 99 (14) :6285-6291
[23]   Kinetics and mechanistic analysis of caustic magnesia hydration [J].
Rocha, SDF ;
Mansur, MB ;
Ciminelli, VST .
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2004, 79 (08) :816-821
[24]  
RUDDLE D., 2013, THESIS NEWCASTLE U
[25]   Removal of struvite to prevent problems associated with its accumulation in wastewater treatment works [J].
Stratful, I ;
Scrimshaw, MD ;
Lester, JN .
WATER ENVIRONMENT RESEARCH, 2004, 76 (05) :437-443
[26]   Conditions influencing the precipitation of magnesium ammonium phosphate [J].
Stratful, I ;
Scrimshaw, MD ;
Lester, JN .
WATER RESEARCH, 2001, 35 (17) :4191-4199