One-electron oxidation of alkyl alkoxybenzenes by ω-fluorosulfonylperfluorodiacyl peroxide

被引：3

作者：

Dong, JH ^{[1
]}

Dou, HY ^{[1
]}

Zhao, CX ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, Coll Chem & Chem Engn, Shanghai 200240, Peoples R China

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2006年 / 127卷 / 02期

关键词：

one-electron oxidation; alkyl alkoxybenzene; omega-fluorosulfonylperfluorodiacyl peroxide; ESR; electron transfer;

D O I：

10.1016/j.jfluchem.2005.11.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The oxidation of p-methylanisole 3a, dialkoxybenzenes 3b, 3c and alkyl dialkoxybenzenes 3d-h by perfluorodi[1-(2-fluorosulfonyl) ethoxy]propionyl peroxide 1 afforded main products 4-omega-fluorosulfonylperfluoroalkyl-4-alkoxy-2,5-cyclohexa-dienones and minor ring omega-fluorosulfonylperfluoroalkylation products. The electron transfer mechanism of the reactions is also proved by ESR detection of the radical cations of the donor molecules. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：205 / 212

页数：8

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