Kondo semiconductors as a novel thermoelectric-cooling material

被引:7
作者
Takabatake, T [1 ]
Suemitsu, T [1 ]
Sasakawa, T [1 ]
Bando, Y [1 ]
Takagi, T [1 ]
Echizen, Y [1 ]
Yoshino, T [1 ]
Umeo, K [1 ]
Iga, F [1 ]
Sera, M [1 ]
Paul, C [1 ]
Berger, S [1 ]
Bauer, E [1 ]
机构
[1] Hiroshima Univ, Dept Quantum Matter, ADSM, Higashihiroshima 7398526, Japan
来源
TWENTIETH INTERNATIONAL CONFERENCE ON THERMOELECTRICS, PROCEEDINGS | 2001年
关键词
D O I
10.1109/ICT.2001.979884
中图分类号
O414.1 [热力学];
学科分类号
摘要
Among rare-earth-based compounds showing the Kondo effect, systems exhibiting a small energy gap in the heavy-electron band are referred to as Kondo semiconductors. We have measured thermoelectric properties of CeNiSn, CeRhSb, CeRhAs, YbB12 and their substituted alloys. The thermopower of CeRhAs has a positive maximum of 130 muV/K at 40 K, while that of YbB12 has a negative peak of -150 muV/K at 10 K. For both CeNiSn and CeRhSb, the electrical resistivity is less than 200 muOmegacm and the thermal conductivity is about 50 mW/Kcm at 60 K. The figure of merit Z for CeRhAs and CeRhSb has the maximum value of 1.0x10(-3)/K at 125 K and 2.2x10(-3)/K at 13 K, respectively, Therefore, these compounds have high potential for a novel thermoelectric cooling material at low temperatures.
引用
收藏
页码:266 / 269
页数:4
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