Incorporation of copper chelate ions into anodic alumina walls

被引：24

作者：

Stepniowski, Wojciech J. ^{[1
]}

Norek, Malgorzata ^{[1
]}

Michalska-Domanska, Marta ^{[1
]}

Nowak-Stepniowska, Agata ^{[2
]}

Bombalska, Aneta ^{[2
]}

Wlodarski, Maksymilian ^{[2
]}

Bojar, Zbigniew ^{[1
]}

机构：

[1] Mil Univ Technol, Fac Adv Technol & Chem, Dept Adv Mat & Technol, PL-00908 Warsaw, Poland

[2] Mil Univ Technol, Inst Optoelect, PL-00908 Warsaw, Poland

来源：

MATERIALS LETTERS | 2013年 / 106卷

关键词：

Anodic aluminum oxide; Nanopores; Self-organization; Ions incorporation; Photoluminescence; Chelate ions; CHROMIC-ACID SOLUTIONS; STRUCTURAL FEATURES; NANOPORE ARRAYS; POROUS ALUMINA; OXALIC-ACID; OXIDE-FILMS; ANODIZATION; PHOTOLUMINESCENCE; TEMPERATURES; MEMBRANES;

D O I：

10.1016/j.matlet.2013.05.016

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Anodic aluminum oxide (MO) is typically applied as a template for nanofabrication. It was found that during anodization the anions of electrolytes are being incorporated into the nanopore walls giving rise to an emission in the UV/VIS range. In this paper, incorporation of copper-EDTA chelate ions was studied. The anodization of all studied samples was carried out in 0.02 M CuSO4+0.02 M EDTA in 2 wt% sulfuric acid, which has provided suitable conditions for self-organized two-step process of MO growth. Nanoporous alumina was formed and studied with Scanning Electron Microscopy. Chemical composition analysis of the anodic alumina revealed that the greater the oxide growth rate, the more copper is being incorporated. The photoluminescence studies confirmed the presence of copper in the AAO pore walls. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：242 / 245

页数：4

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