Two-Dimensional Networks of [AuCl4]- and [AuBr4]- Anions

被引：15

作者：

Doering, Cindy ^{[1
]}

Jones, Peter G. ^{[1
]}

机构：

[1] Tech Univ Carolo Wilhelmina Braunschweig, Inst Inorgan & Analyt Chem, Hagenring 30, D-38106 Braunschweig, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2016年 / 642卷 / 17期

关键词：

X-ray structure; Tetrachloridoaurate; Tetrabromidoaurate; Halogen contacts; Gold; CRYSTAL-STRUCTURE; HALOGEN; COMPLEXES;

D O I：

10.1002/zaac.201600199

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several salts of protonated amines and aza-aromatics with [AuCl4](-) and [AuBr4](-) anions contain two-dimensional ("square") anionic networks that display short halogenhalogen contacts. The Au-4 quadrilaterals formed by neighboring anions of the networks are to a good approximation squares, with sides of around 7.5 for teachloridoauratesn8 for .

引用

页码：930 / 936

页数：7

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