Two-Dimensional Networks of [AuCl4]- and [AuBr4]- Anions

被引:15
作者
Doering, Cindy [1 ]
Jones, Peter G. [1 ]
机构
[1] Tech Univ Carolo Wilhelmina Braunschweig, Inst Inorgan & Analyt Chem, Hagenring 30, D-38106 Braunschweig, Germany
来源
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2016年 / 642卷 / 17期
关键词
X-ray structure; Tetrachloridoaurate; Tetrabromidoaurate; Halogen contacts; Gold; CRYSTAL-STRUCTURE; HALOGEN; COMPLEXES;
D O I
10.1002/zaac.201600199
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Several salts of protonated amines and aza-aromatics with [AuCl4](-) and [AuBr4](-) anions contain two-dimensional ("square") anionic networks that display short halogenhalogen contacts. The Au-4 quadrilaterals formed by neighboring anions of the networks are to a good approximation squares, with sides of around 7.5 for teachloridoauratesn8 for .
引用
收藏
页码:930 / 936
页数:7
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