Octanuclear μ-oxo N,N-diethylcarbamato derivatives of titanium(IV) obtained by a high-yielding hydrolytic process

被引：20
作者：
Dell'Amico, Daniela Belli [1 ]
Calderazzo, Fausto [1 ]
Costa, Lorenzo [2 ]
Franchi, Emanuela [1 ]
Gini, Lucia [2 ]
Labella, Luca [1 ]
Marchetti, Fabio [1 ]
机构：
[1] Univ Pisa, Dipartimento Chim & Chim Ind, I-56126 Pisa, Italy
[2] Degussa Novara Technol SpA, I-28100 Novara, Italy
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2008年 / 890卷 / 1-3期
关键词：
Carbamato complexes; Titanium; Host-guest; Synthesis and crystal structure;
D O I：
10.1016/j.molstruc.2008.04.041
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A crystallographically characterized octanuclear mu-oxo derivative of titanium(IV), Ti8O8(O2CNEt2)(16), as obtained by controlled hydrolysis of Ti(O2CNEt2)(4) in DME, was shown to exhibit sequestering properties towards' [NH2Et2][O2CNEt2]. (c) 2008 Published by Elsevier B.V.
引用
收藏
页码：295 / 297
页数：3
相关论文
共 34 条
  • [1] Abram U., 1997, J CHEM SOC CHEM COMM, P1941
  • [2] AGOSTINELLI E, 1988, GAZZ CHIM ITAL, V118, P729
  • [3] Atkinson IM, 1999, CHEM COMMUN, P285
  • [4] OCTAMERIC TITANIUM OXO METALLACYCLE WITH HOST-GUEST INTERACTIONS
    BARROW, H
    BROWN, DA
    ALCOCK, NW
    CLASE, HJ
    WALLBRIDGE, MGH
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (12) : 1231 - 1232
  • [5] Supramolecular self-assembly of a toroidal inclusion complex, [NH4][Co8(MeCO2)8(OMe)16][PF6]
    Beattie, JK
    Hambley, TW
    Klepetko, JA
    Masters, AF
    Turner, P
    [J]. CHEMICAL COMMUNICATIONS, 1998, (01) : 45 - 46
  • [6] DEOXYGENATION OF CARBON-DIOXIDE TO DIETHYLFORMAMIDE IN THE ZN/HNET2/CO2 SYSTEM - CRYSTAL AND MOLECULAR-STRUCTURE OF [ZN4O(O2CNET2)6]
    BELFORTE, A
    CALDERAZZO, F
    ENGLERT, U
    STRAHLE, J
    [J]. INORGANIC CHEMISTRY, 1991, 30 (19) : 3778 - 3781
  • [7] SYNTHESIS OF N,N-DIALKYLCARBAMATO COMPLEXES OF GROUP-4 METALS (TI, ZR, HF) BY THE METAL CHLORIDE-NHR2-CO2 SYSTEM (R = ET OR PRI) - CRYSTAL AND MOLECULAR-STRUCTURE OF [HF(O2CNPRI2)4]
    CALDERAZZO, F
    IANELLI, S
    PAMPALONI, G
    PELIZZI, G
    SPERRLE, M
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, : 693 - 698
  • [8] DIALKYL-CARBAMATE COMPLEXES OF TRANSITION-ELEMENTS .2. CRYSTAL AND MOLECULAR-STRUCTURE OF DI-MU3-OXO-DODECA(DIETHYLCARBAMATO)TETRAURANIUM(IV)
    CALDERAZZO, F
    DELLAMICO, G
    PASQUALI, M
    PEREGO, G
    [J]. INORGANIC CHEMISTRY, 1978, 17 (02) : 474 - 479
  • [9] N,N-dimethylcarbamato complexes of zinc
    Dell'Amico, Daniela Belli
    Calderazzo, Fausto
    Labella, Luca
    Marchetti, Fabio
    Mazzoncini, Ilaria
    [J]. INORGANICA CHIMICA ACTA, 2006, 359 (10) : 3371 - 3374
  • [10] A facile synthesis of Zn4([μ4-O)(O2CNMe2)6
    Dell'Amico, DB
    Calderazzo, F
    Labella, L
    Marchetti, F
    [J]. INORGANICA CHIMICA ACTA, 2003, 350 : 661 - 664
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