Production of value-added chemicals from bio-oil via acid catalysis coupled with liquid-liquid extraction

被引:64
作者
Hu, Xun [1 ]
Mourant, Daniel [1 ]
Gunawan, Richard [1 ]
Wu, Liping [1 ]
Wang, Yi [1 ]
Lievens, Caroline [1 ]
Li, Chun-Zhu [1 ]
机构
[1] Curtin Univ Technol, Fuels & Energy Technol Inst, Perth, WA 6845, Australia
关键词
FAST PYROLYSIS; BIOMASS; ESTERIFICATION; DEHYDRATION; HYDROLYSIS; LEVULINATE; CONVERSION; FRUCTOSE; ESTERS; SUGARS;
D O I
10.1039/c2ra21597g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Sugar/sugar derivatives in bio-oil can be effectively separated from aromatics via water/chloroform extraction. Subsequent acid-treatment in methanol converts the sugars into levulinic acid/ester and the sugar derivatives into fuel additives. Further extraction with CH2Cl2/CHCl3 could efficiently separate methyl levulinate and levulinic acid from other products.
引用
收藏
页码:9366 / 9370
页数:5
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