Production of value-added chemicals from bio-oil via acid catalysis coupled with liquid-liquid extraction

被引:63
作者
Hu, Xun [1 ]
Mourant, Daniel [1 ]
Gunawan, Richard [1 ]
Wu, Liping [1 ]
Wang, Yi [1 ]
Lievens, Caroline [1 ]
Li, Chun-Zhu [1 ]
机构
[1] Curtin Univ Technol, Fuels & Energy Technol Inst, Perth, WA 6845, Australia
关键词
FAST PYROLYSIS; BIOMASS; ESTERIFICATION; DEHYDRATION; HYDROLYSIS; LEVULINATE; CONVERSION; FRUCTOSE; ESTERS; SUGARS;
D O I
10.1039/c2ra21597g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Sugar/sugar derivatives in bio-oil can be effectively separated from aromatics via water/chloroform extraction. Subsequent acid-treatment in methanol converts the sugars into levulinic acid/ester and the sugar derivatives into fuel additives. Further extraction with CH2Cl2/CHCl3 could efficiently separate methyl levulinate and levulinic acid from other products.
引用
收藏
页码:9366 / 9370
页数:5
相关论文
共 38 条
[1]   Exploring the ruthenium catalysed synthesis of γ-valerolactone in alcohols and utilisation of mild solvent-free reaction conditions [J].
Al-Shaal, Mohammad G. ;
Wright, William R. H. ;
Palkovits, Regina .
GREEN CHEMISTRY, 2012, 14 (05) :1260-1263
[2]   Catalytic conversion of biomass to biofuels [J].
Alonso, David Martin ;
Bond, Jesse Q. ;
Dumesic, James A. .
GREEN CHEMISTRY, 2010, 12 (09) :1493-1513
[3]   Kinetics of the decomposition of fructose catalyzed by hydrochloric acid in subcritical water: Formation of 5-hydroxymethylfurfural, levulinic, and formic acids [J].
Asghari, Feridoun Salak ;
Yoshida, Hiroyuki .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (23) :7703-7710
[4]   Extraction and hydrolysis of levoglucosan from pyrolysis oil [J].
Bennett, Nicole M. ;
Helle, Steve S. ;
Duff, Sheldon J. B. .
BIORESOURCE TECHNOLOGY, 2009, 100 (23) :6059-6063
[5]   Aromatic Production from Catalytic Fast Pyrolysis of Biomass-Derived Feedstocks [J].
Carlson, Torren R. ;
Tompsett, Geoffrey A. ;
Conner, William C. ;
Huber, George W. .
TOPICS IN CATALYSIS, 2009, 52 (03) :241-252
[6]   Liquid-phase catalytic transfer hydrogenation and cyclization of levulinic acid and its esters to γ-valerolactone over metal oxide catalysts [J].
Chia, Mei ;
Dumesic, James A. .
CHEMICAL COMMUNICATIONS, 2011, 47 (44) :12233-12235
[7]   Char Formation Mechanism in Supercritical Water Gasification Process: A Study of Model Compounds [J].
Chuntanapum, Athika ;
Matsumura, Yukihiko .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (09) :4055-4062
[8]  
CLERICI MG, 1991, APPL CATAL, V68, P249
[9]   Converting carbohydrates to bulk chemicals and fine chemicals over heterogeneous catalysts [J].
Climent, Maria J. ;
Corma, Avelino ;
Iborra, Sara .
GREEN CHEMISTRY, 2011, 13 (03) :520-540
[10]   Chemical routes for the transformation of biomass into chemicals [J].
Corma, Avelino ;
Iborra, Sara ;
Velty, Alexandra .
CHEMICAL REVIEWS, 2007, 107 (06) :2411-2502