Chemiluminescence of Ru(bpy)32+* in the reaction of electron transfer from Ph2CNa to Ru(bpy)33+ in a solution

被引：1

作者：

Bulgakov, RG ^{[1
]}

Kuleshov, SP ^{[1
]}

Usmanov, TS ^{[1
]}

Mustafin, BA ^{[1
]}

机构：

[1] Bashkortostan Republ Acad Sci, Inst Petrochem & Catalysis, Ufa 450054, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 02期

关键词：

chemiluminescence; photoluminescence; ruthenium complex; organometallic compounds;

D O I：

10.1007/BF02494551

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conditions for the generation of the Ru(bpy)(3)(3+) complex in organic solvents (Me3CN or MeNO2) in the presence of small amounts of H2SO4 were found. Chemiluminescence was observed in the reaction of Ru(bpy)(3)(3+) With Ph3Na in a THF-MeCN mixture. The chemiluminescence emitter was identified as Ru(bpy)(3)(2+)*. This emitter forms in the excited state in the elementary reaction of electron transfer from the Ph3C- anion to Ru(bpy)(3)(3+).

引用

页码：291 / 293

页数：3

共 50 条

[31] Effect of water content in the Nafion matrix and the pH of the electrolyte solution on the charge transfer in the oxidation of the Ru(bpy)32+ complex
Zhang, J
Zhao, F
Kaneko, M
ELECTROCHIMICA ACTA, 1999, 44 (19) : 3367 - 3375
[32] Enhancement of magnetic field effect in Ru(bpy)32+/MV2+ system by Ru(bpy)32+-Ag+ exciplex formation
Fodor, L
Horváth, A
Hötzer, KA
Walbert, S
Steiner, UE
CHEMICAL PHYSICS LETTERS, 2000, 316 (5-6) : 411 - 418
[33] Quenching of Excited Ru(bpy)32+ in Nafion Ionomer Solution and in Nafion Membrane
Shioyama, Hiroshi
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2009, 515 : 230 - 238
[34] Chemiluminescence oscillation in the Belousov-Zhabotinsky (B-Z) reaction catalyzed by Ru(bpy)32+ complex
Han, He-You
He, Zhi-Ke
Zeng, Yun-E
Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities, 2006, 27 (11): : 2152 - 2155
[35] Chemiluminescence oscillation in the Belousov-Zhabotinsky(B-Z) reaction catalyzed by Ru(bpy)32+ complex
Han He-You
He Zhi-Ke
Zeng Yun-E
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2006, 27 (11): : 2152 - 2155
[36] PHOTOCATALYSIS OF THE PSCHORR REACTION BY RU(BPY)32+ IN THE FLUORENONE, FLUORENE AND DIBENZOFURAN SERIES
CANOYELO, H
DERONZIER, A
JOURNAL OF PHOTOCHEMISTRY, 1987, 37 (02): : 315 - 321
[37] Hot electron-induced electrogenerated chemiluminescence of Ru(bpy)32+ chelate at oxide covered aluminum electrodes
Ala-Kleme, T
Kulmala, S
Väre, L
Juhala, P
Helin, M
ANALYTICAL CHEMISTRY, 1999, 71 (24) : 5538 - 5543
[38] Study on MnO2 nano-materials Catalyze Electrogenerated Chemiluminescence of Ru(bpy)32+
Guo, Weiling
Li, Enzhong
Wang, Haidou
NANOTECHNOLOGY AND PRECISION ENGINEERING, PTS 1 AND 2, 2013, 662 : 68 - +
[39] A Method Based on Ru(bpy)33+ Electrogenerated Chemiluminescence for Assessment of Antioxidant Property of Naturally Occurring Antioxidants
Nobushi, Yasuhito
Asamoto, Hiromichi
Uchikura, Kazuo
YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN, 2019, 139 (02): : 309 - 315
[40] Chemiluminescence parameters of peroxynitrous acid in the presence of short-chain alcohols and Ru(bpy)32+
Wei, Lijun
Xia, Huifen
Wang, Zhaopin
Yuan, Ping
Zhou, Tong
Zhang, Baojun
Cheng, Xianglei
CHEMICAL PAPERS, 2011, 65 (06): : 761 - 768

← 1 2 3 4 5 →