Chemiluminescence of Ru(bpy)32+* in the reaction of electron transfer from Ph2CNa to Ru(bpy)33+ in a solution

被引：1

作者：

Bulgakov, RG ^{[1
]}

Kuleshov, SP ^{[1
]}

Usmanov, TS ^{[1
]}

Mustafin, BA ^{[1
]}

机构：

[1] Bashkortostan Republ Acad Sci, Inst Petrochem & Catalysis, Ufa 450054, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 02期

关键词：

chemiluminescence; photoluminescence; ruthenium complex; organometallic compounds;

D O I：

10.1007/BF02494551

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conditions for the generation of the Ru(bpy)(3)(3+) complex in organic solvents (Me3CN or MeNO2) in the presence of small amounts of H2SO4 were found. Chemiluminescence was observed in the reaction of Ru(bpy)(3)(3+) With Ph3Na in a THF-MeCN mixture. The chemiluminescence emitter was identified as Ru(bpy)(3)(2+)*. This emitter forms in the excited state in the elementary reaction of electron transfer from the Ph3C- anion to Ru(bpy)(3)(3+).

引用

页码：291 / 293

页数：3

共 50 条

[21] Electrogenerated chemiluminescence of a Ru(bpy)32+/arginine system: a specific and sensitive detection of acetaminophen
Xiao, Yi
Wang, Guofang
Yi, Haomin
Chen, Suhua
Wu, Qinyu
Zhang, Siyi
Deng, Kexin
Zhang, Simeng
Shi, Zi-Qi
Yang, Xiaoping
RSC ADVANCES, 2022, 12 (05) : 3157 - 3164
[22] Organosilicate thin film containing Ru(bpy)32+ for an electrogenerated chemiluminescence (ECL) sensor
Lee, JK
Lee, SH
Kim, M
Kim, H
Kim, DH
Lee, WY
CHEMICAL COMMUNICATIONS, 2003, (13) : 1602 - 1603
[23] Electrogenerated Chemiluminescence Biosensor Based on Ru(bpy)32+ Doped Mesoporous Silica Nanoparticles
Wang Yong-Hong
He Xiao-Xiao
Wang Ke-Min
Su Jing
Chen Zhi-Feng
Yan Gen-Ping
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2012, 33 (06): : 1162 - 1166
[24] Electrogenerated Chemiluminescence (ECL) Quenching of the Ru (bpy)32+/TPrA System by the Explosive TNT
Parajuli, Suman
Jing, Xiaohui
Miao, Wujian
ELECTROCHIMICA ACTA, 2015, 180 : 196 - 201
[25] MICELLAR EFFECT ON ELECTRON-TRANSFER .1. ELECTRON-TRANSFER OF RU(BPY)33+ IN MICELLAR SOLUTIONS
PELIZZETTI, E
PRAMAURO, E
INORGANIC CHEMISTRY, 1979, 18 (03) : 882 - 883
[26] Photoinduced electron transfer between Ru(bpy)32+ and donor/acceptor in a polyethylene oxide film
Abe, T
Ohshima, T
Nagai, K
Ishikawa, S
Kaneko, M
REACTIVE & FUNCTIONAL POLYMERS, 1998, 37 (1-3): : 133 - 137
[27] Photoinduced electron transfer between Ru(bpy)32+ and donor/acceptor in a polyethylene oxide film
Abe, Toshiyuki
Ohshima, Takao
Nagai, Keiji
Ishikawa, Shigenobu
Kaneko, Masao
Reactive and Functional Polymers, 1998, 37 (1-3): : 133 - 137
[28] Electrogenerated chemiluminescence triggered by electroseparation of Ru(bpy)32+ across a supported liquid membrane
Crespo, Gaston A.
Mistlberger, Guenter
Bakker, Eric
CHEMICAL COMMUNICATIONS, 2011, 47 (42) : 11644 - 11646
[29] Hollow organosilica spheres as hosts:: Photoinduced electron transfer between Ru(bpy)32+ and methylviologen
Ferrer, Belen
Llabres i Xamena, Francesc X.
Garcia, Hermenegildo
INORGANICA CHIMICA ACTA, 2007, 360 (03) : 1017 - 1022
[30] Redox-switchable direction of photoinduced electron transfer in an Ru(bpy)32+ -: Viologen dyad
Lomoth, R
Häupl, T
Johansson, O
Hammarström, L
CHEMISTRY-A EUROPEAN JOURNAL, 2002, 8 (01) : 102 - 110

← 1 2 3 4 5 →