Chemiluminescence of Ru(bpy)32+* in the reaction of electron transfer from Ph2CNa to Ru(bpy)33+ in a solution

被引：1

作者：

Bulgakov, RG ^{[1
]}

Kuleshov, SP ^{[1
]}

Usmanov, TS ^{[1
]}

Mustafin, BA ^{[1
]}

机构：

[1] Bashkortostan Republ Acad Sci, Inst Petrochem & Catalysis, Ufa 450054, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 02期

关键词：

chemiluminescence; photoluminescence; ruthenium complex; organometallic compounds;

D O I：

10.1007/BF02494551

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conditions for the generation of the Ru(bpy)(3)(3+) complex in organic solvents (Me3CN or MeNO2) in the presence of small amounts of H2SO4 were found. Chemiluminescence was observed in the reaction of Ru(bpy)(3)(3+) With Ph3Na in a THF-MeCN mixture. The chemiluminescence emitter was identified as Ru(bpy)(3)(2+)*. This emitter forms in the excited state in the elementary reaction of electron transfer from the Ph3C- anion to Ru(bpy)(3)(3+).

引用

页码：291 / 293

页数：3

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