Chemiluminescence of Ru(bpy)32+* in the reaction of electron transfer from Ph2CNa to Ru(bpy)33+ in a solution

被引：1
|
作者：
Bulgakov, RG [1 ]
Kuleshov, SP [1 ]
Usmanov, TS [1 ]
Mustafin, BA [1 ]
机构：
[1] Bashkortostan Republ Acad Sci, Inst Petrochem & Catalysis, Ufa 450054, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 02期
关键词：
chemiluminescence; photoluminescence; ruthenium complex; organometallic compounds;
D O I：
10.1007/BF02494551
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Conditions for the generation of the Ru(bpy)(3)(3+) complex in organic solvents (Me3CN or MeNO2) in the presence of small amounts of H2SO4 were found. Chemiluminescence was observed in the reaction of Ru(bpy)(3)(3+) With Ph3Na in a THF-MeCN mixture. The chemiluminescence emitter was identified as Ru(bpy)(3)(2+)*. This emitter forms in the excited state in the elementary reaction of electron transfer from the Ph3C- anion to Ru(bpy)(3)(3+).
引用
收藏
页码：291 / 293
页数：3
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