Carbohydrate Derived Organogelators and the Corresponding Functional Gels Developed in Recent Time

被引:35
作者
Basu, Nabamita [1 ]
Chakraborty, Arijit [2 ]
Ghosh, Rina [3 ]
机构
[1] Nabagram Hiralal Paul Coll, Dept Chem, Konnagar 712246, W Bengal, India
[2] Acharya BN Seal Coll, Dept Chem, Cooch Behar 736101, W Bengal, India
[3] Jadavpur Univ, Dept Chem, Kolkata 700032, India
关键词
carbohydrates; organogelators; gels; sugars; ROOM-TEMPERATURE GELATION; MOLECULAR-WEIGHT GELATORS; MASS ORGANIC GELATORS; SUPRAMOLECULAR GELS; TOPOCHEMICAL SYNTHESIS; SORBITAN MONOSTEARATE; DRUG-DELIVERY; SOFT MATTER; OIL; ASSEMBLIES;
D O I
10.3390/gels4020052
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Owing to their multifarious applicability, studies of molecular and supramolecular gelators and their corresponding gels have gained momentum, particularly in the last two decades. Hydrophobic-hydrophilic balance, different solvent parameters, gelator-gelator and gelator-solvent interactions, including different noncovalent intermolecular interactive forces like H-bonding, ionic interactions, pi-pi interactions, van derWaals interactions, etc., cause the supramolecular gel assembly of micro and nano scales with different types of morphologies, depending on the gelator, solvent, and condition of gelation. These gel structures can be utilized for making template inorganic superstructures for potential application in separation, generation of nanocomposite materials, and other applications like self-healing, controlled drug encapsulation, release and delivery, as structuring agents, oil-spill recovery, for preparation of semi-conducting fabrics, and in many other fields. Sugars, being easily available, inexpensive, and nontoxic natural resources with multi functionality and well-defined chirality are attractive starting materials for the preparation of sugar-based gelators. This review will focus on compilation of sugar derived organogelators and the corresponding gels, along with the potential applications that have been developed and published recently between January 2015 and March 2018.
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页数:34
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