Three-component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of C=C Bonds Mediated by Photoredox Catalysts

被引:478
作者
Yasu, Yusuke [1 ]
Koike, Takashi [1 ]
Akita, Munetaka [1 ]
机构
[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
关键词
fluorine; homogeneous catalysis; photochemistry; radical reactions; synthetic methods; VISIBLE-LIGHT PHOTOCATALYSIS; ELECTROPHILIC TRIFLUOROMETHYLATION; RUTHENIUM(II) COMPLEX; ALDEHYDES; FLUORINE; PERFLUOROALKYLATION; ORGANOCATALYSIS; ALKYLATION; PANOMIFENE; MOLECULES;
D O I
10.1002/anie.201205071
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
引用
收藏
页码:9567 / 9571
页数:5
相关论文
共 55 条
  • [1] Recent Progress in Catalytic Aromatic Trifluoromethylation
    Amii, Hideki
    [J]. JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2011, 69 (07) : 752 - 762
  • [2] [Anonymous], 2005, ANGEW CHEM
  • [3] [Anonymous], 2004, CHEMBIOCHEM, V5, P570
  • [4] Besset T., 2012, ANGEW CHEM, V124, P5134
  • [5] Tamed Arene and Heteroarene Trifluoromethylation
    Besset, Tatiana
    Schneider, Cedric
    Cahard, Dominique
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (21) : 5048 - 5050
  • [6] Stereoselective construction of the 1,1,1-trifluoroisopropyl moiety by asymmetric hydrogenation of 2-(trifluoromethyl)allylic alcohols and its application to the synthesis of a trifluoromethylated amino diol
    Chen, Qi
    Qing, Feng-Ling
    [J]. TETRAHEDRON, 2007, 63 (48) : 11965 - 11972
  • [7] Novel 10-I-3 hypervalent iodine-based compounds for electrophilic trifluoromethylation
    Eisenberger, P
    Gischig, S
    Togni, A
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (09) : 2579 - 2586
  • [8] Photochemistry and photophysics of coordination compounds: Iridium
    Flamigni, Lucia
    Barbieri, Andrea
    Sabatini, Cristiana
    Ventura, Barbara
    Barigelletti, Francesco
    [J]. PHOTOCHEMISTRY AND PHOTOPHYSICS OF COORDINATION COMPOUNDS II, 2007, 281 : 143 - 203
  • [9] Catalysis for fluorination and trifluoromethylation
    Furuya, Takeru
    Kamlet, Adam S.
    Ritter, Tobias
    [J]. NATURE, 2011, 473 (7348) : 470 - 477
  • [10] Hiyama T., 2013, ORGANOFLUORINE COMPO