Recent advances in asymmetric intra- and intermolecular halofunctionalizations of alkenes

被引：213

作者：

Cheng, Yi An ^{[1
]}

Yu, Wesley Zongrong ^{[1
]}

Yeung, Ying-Yeung ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2014年 / 12卷 / 15期

关键词：

CHIRAL PHOSPHORIC-ACID; HALONIUM ION FORMATION; STABLE CARBONIUM IONS; NEIGHBORING HALOGEN PARTICIPATION; AMINO-THIOCARBAMATE CATALYST; PHASE-TRANSFER CATALYSIS; OLEFINIC ACIDS; BRONSTED ACID; ENANTIOSELECTIVE BROMOAMINOCYCLIZATION; BIFUNCTIONAL CATALYST;

D O I：

10.1039/c3ob42335b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review seeks to provide coverage on recent advances in catalytic enantioselective halofunctionalization of alkenes. The aim is to give an overview of various reports, highlighting the new reaction types and strategies developed during the past two years. The scope and challenges of intra-and intermolecular reaction variants are discussed as well.

引用

页码：2333 / 2343

页数：11

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