trans-Bis(5,5-diphenylhydantoinato-κN3)bis(propane-1,2-diamine-κ2N,N′)nickel(II)

被引：1
作者：
Hu, Xilan
Xu, Xingyou
Wang, Daqi
Li, Xiaojiao
机构：
[1] Huaihai Institute of Technology
[2] College of Chemistry and Chemical Engineering, Liaocheng University
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536808038749
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title complex, [Ni(pht)(2)(pn)(2)] (pht is 5,5-diphenylhydantoinate and pn is propane-1,2-diamine) or [Ni(C(15)H(11)N(2)O(2))(2)(C(3)H(10)N(2))(2)], contains one-half [Ni(pht)(2)(pn)(2)] molecule. The Ni(II) atom is situated on a crystallographic center of inversion and shows a distorted octahedral coordination geometry. A three-dimensional network structure is assembled by inter-and intramolecular N-H center dot center dot center dot O = C interactions.
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页码：M1636 / U1446
页数：12
相关论文
共 8 条
  • [1] trans-Bis(2,2-diphenylethylaminexN)bis(5,5-diphenylhydantoinato- κN3)copper(II) and its chloroform disolvate
    Akitsu, T
    Einaga, Y
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2005, 61 : M183 - M186
  • [2] Structures of bis(5,5-diphenylhydantoinato)copper(II) complexes with primary amines involving square pyramidal CuN4O chromophores
    Akitsu, T
    Komorita, S
    Kushi, Y
    Li, CM
    Kanehisa, N
    Kai, Y
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1997, 70 (04) : 821 - 827
  • [3] trans-Diaquabis(5,5-diphenylhydantoinato-κN3)copper(II)
    Hu, Xi-Lan
    Xu, Xing-You
    Wang, Da-Qi
    Xu, Tong-Tao
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M1922 - M1923
  • [4] Bis(5,5-diphenylhydantoinato-κN3)copper(II) 2-methyl-3,4,5,6-tetrahydropyrimidine solvate
    Hu, Xilan
    Xu, Xingyou
    Xu, Tongtao
    Wang, Daqi
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M2221 - M2223
  • [5] Interaction of anticonvulsant drugs with metals:: a semi-empirical molecular orbital study of phenytoin-zinc(II) complexation
    Milne, P
    Hô, M
    Weaver, DF
    [J]. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 1999, 492 : 19 - 28
  • [6] Sheldrick G.M., 1996, SADABS VERSION 2008
  • [7] A short history of SHELX
    Sheldrick, George M.
    [J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122
  • [8] *SIEM AN XR INSTR, 1996, SMART SAINT
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