One-Pot Synthesis of Fluorescent Carbon Dots from Orange Waste Peels

被引:430
作者
Prasannan, Adhimoorthy [1 ]
Imae, Toyoko [1 ,2 ]
机构
[1] Natl Taiwan Univ Sci & Technol, Grad Inst Appl Sci & Technol, Taipei 10607, Taiwan
[2] Natl Taiwan Univ Sci & Technol, Dept Chem Engn, Taipei 10607, Taiwan
关键词
GRAPHENE QUANTUM DOTS; HYDROTHERMAL CARBONIZATION; D-FRUCTOSE; NANODOTS; ZNO; NANOPARTICLES; GLUCOSE; BIOMASS;
D O I
10.1021/ie402421s
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A simple and facile one-pot synthesis of fluorescent carbon dots from orange waste peels was performed using the hydrothermal carbonization method at a mild temperature (180 degrees C). The chemical composition and morphological feature of the obtained carbon dots (C-dots) were characterized using various spectroscopies and a transmission electron microscopy. The prepared hydrothermal carbons were amorphous in nature, and clusters of polyaromatic hydrocarbons included a large quantity of oxygen functional groups. A composite of C-dot with ZnO was used as a photocatalyst for degradation of naphthol blue-black azo dye under UV irradiation, and the superior photocatalytic activity was demonstrated. Overall, the present preparation method of C-dots takes on meaning in the area of green synthesis in aqueous solutions, and the product has great potential as a component material in the development of a remarkably efficient catalytic system.
引用
收藏
页码:15673 / 15678
页数:6
相关论文
共 35 条
[1]   Synthesis and Characterization of Carbonaceous Materials from Saccharides (Glucose and Lactose) and Two Waste Biomasses by Hydrothermal Carbonization [J].
Aydincak, Kivanc ;
Yumak, Tugrul ;
Sinag, Ali ;
Esen, Bekir .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (26) :9145-9152
[2]   Structural Characterization of Hydrothermal Carbon Spheres by Advanced Solid-State MAS 13C NMR Investigations [J].
Baccile, Niki ;
Laurent, Guillaume ;
Babonneau, Florence ;
Fayon, Franck ;
Titirici, Maria-Magdalena ;
Antonietti, Markus .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (22) :9644-9654
[3]   Luminescent Carbon Nanodots: Emergent Nanolights [J].
Baker, Sheila N. ;
Baker, Gary A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (38) :6726-6744
[4]   Synthesis of graphene-ZnO nanorod nanocomposites with improved photoactivity and anti-photocorrosion [J].
Chen, Zhang ;
Zhang, Nan ;
Xu, Yi-Jun .
CRYSTENGCOMM, 2013, 15 (15) :3022-3030
[5]   Hydrothermal Carbon from Biomass: Structural Differences between Hydrothermal and Pyrolyzed Carbons via 13C Solid State NMR [J].
Falco, Camillo ;
Caballero, Fernando Perez ;
Babonneau, Florence ;
Gervais, Christel ;
Laurent, Guillaume ;
Titirici, Maria-Magdalena ;
Baccile, Niki .
LANGMUIR, 2011, 27 (23) :14460-14471
[6]   Engineering Carbon Materials from the Hydrothermal Carbonization Process of Biomass [J].
Hu, Bo ;
Wang, Kan ;
Wu, Liheng ;
Yu, Shu-Hong ;
Antonietti, Markus ;
Titirici, Maria-Magdalena .
ADVANCED MATERIALS, 2010, 22 (07) :813-828
[7]   Solvent Effect on Pathways and Mechanisms for D-Fructose Conversion to 5-Hydroxymethyl-2-furaldehyde: In Situ 13C NMR Study [J].
Kimura, Hiroshi ;
Nakahara, Masaru ;
Matubayasi, Nobuyuki .
JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 117 (10) :2102-2113
[8]   In Situ Kinetic Study on Hydrothermal Transformation of D-Glucose into 5-Hydroxymethylfurfural through D-Fructose with 13C NMR [J].
Kimura, Hiroshi ;
Nakahara, Masaru ;
Matubayasi, Nobuyuki .
JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 115 (48) :14013-14021
[9]   Visible light active photocatalysis on block copolymer induced strings of ZnO nanoparticles doped with carbon [J].
Kochuveedu, Saji Thomas ;
Jang, Yoon Hee ;
Jang, Yu Jin ;
Kim, Dong Ha .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (03) :898-905
[10]   Carbon nanodots: synthesis, properties and applications [J].
Li, Haitao ;
Kang, Zhenhui ;
Liu, Yang ;
Lee, Shuit-Tong .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (46) :24230-24253