Influences of re-sintering on the structure and electrochemical performance of LiNi1/3Co1/3Mn1/3O2

被引:0
作者
Yuan, Li [1 ]
Zhang, Yun [1 ]
Liu, Wenjing [1 ]
Wang, Fu [1 ]
Lu, Chao [1 ]
机构
[1] Sichuan Univ, Coll Mat Sci & Engn, Chengdu 610064, Peoples R China
来源
LEADING EDGE OF MICRO-NANO SCIENCE AND TECHNOLOGY | 2013年 / 669卷
关键词
re-sintering; LiNi1/3Co1/3Mn1/3O2; cathode materials; lithium-ion battery; LICO1/3NI1/3MN1/3O2;
D O I
10.4028/www.scientific.net/AMR.669.355
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The influences of re-sintering on the structure and electrochemical performance of LiNi1/3Co1/3Mn1/3O2 were researched in this paper. The synthesized materials were characterized and tested by means of X-ray diffraction (XRD) and electrochemical measurements respectively. It was found that the re-sintered samples with better well-ordered layered structure, more perfect crystallization and more complete crystal structure will be formed with increasing temperature. Moreover, reasonable re-sintering time was required. The materials re-sintered at 860 degrees C for 2h exhibited the best electrochemical performance, including high initial discharge capacity of 150.6 mAh.g(-1) and coulomb efficiency of 84% at 0.2C rate.
引用
收藏
页码:355 / 359
页数:5
相关论文
共 11 条
[1]   Effects of cation mixing on the electrochemical lithium intercalation reaction into porous Li1-delta Ni1-yCoyO2 electrodes [J].
Choi, YM ;
Pyun, SI ;
Moon, SI .
SOLID STATE IONICS, 1996, 89 (1-2) :43-52
[2]   Structural and electrochemical properties of LiNi1/3Mn1/3Co1/3O2-xFx prepared by solid state reaction [J].
Kageyama, Masaya ;
Li, Decheng ;
Kobayakawa, Koichi ;
Sato, Yuichi ;
Lee, Yun-Sung .
JOURNAL OF POWER SOURCES, 2006, 157 (01) :494-500
[3]  
Kelley T., 2001, LITHIUM MANGANESE OX, Patent No. 6322744
[4]   Electrochemically active LiCoO2 and LiNiO2 made by cationic exchange under hydrothermal conditions [J].
Larcher, D ;
Palacin, MR ;
Amatucci, GG ;
Tarascon, JM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (02) :408-417
[5]   Synthetic optimization of Li[Ni1/3Co1/3Mn1/3]O2 via co-precipitation [J].
Lee, MH ;
Kang, Y ;
Myung, ST ;
Sun, YK .
ELECTROCHIMICA ACTA, 2004, 50 (04) :939-948
[6]   Structural and thermal properties of LiNi0.6-xMgxCo0.25Mn0.15O2 cathode materials [J].
Liao, Pei-Yun ;
Duh, Jenq-Gong ;
Sheu, Hwo-Shuenn .
JOURNAL OF POWER SOURCES, 2008, 183 (02) :766-770
[7]   Structural and electrochemical properties of nanosize layered Li[Li1/5Ni1/10Co1/5Mn1/2]O2 [J].
Park, KS ;
Cho, MH ;
Jin, SJ ;
Nahm, KS .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (08) :A239-A241
[8]   STRUCTURE AND ELECTROCHEMISTRY OF LIXFEYNI1-YO2 [J].
REIMERS, JN ;
ROSSEN, E ;
JONES, CD ;
DAHN, JR .
SOLID STATE IONICS, 1993, 61 (04) :335-344
[9]   Synthesis of LiCo1/3Ni1/3Mn1/3O2 as a cathode material for lithium ion battery by water-in-oil emulsion method [J].
Tong, DG ;
Lai, QY ;
Wei, NN ;
Tang, AD ;
Tang, LX ;
Huang, KL ;
Ji, XY .
MATERIALS CHEMISTRY AND PHYSICS, 2005, 94 (2-3) :423-428
[10]   Structural, physical and electrochemical characterisation of LiNixCo1-xO2 solid solutions [J].
Wang, GX ;
Horvat, J ;
Bradhurst, DH ;
Liu, HK ;
Dou, SX .
JOURNAL OF POWER SOURCES, 2000, 85 (02) :279-283