Fabrication of organic-inorganic semiconductor composites utilizing the different aggregation states of a single amphiphilic dendrimer

被引：21
作者：
Donners, JJJM
Hoogenboom, R
Schenning, APHJ
van Hal, PA
Nolte, RJM
Meijer, EW
Sommerdijk, NAJM
机构：
[1] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands
[2] Univ Nijmegen, Organ Chem Lab, Nijmegen, Netherlands
来源：
LANGMUIR | 2002年 / 18卷 / 07期
关键词：
D O I：
10.1021/la010997z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A third generation poly(propylene imine) dendrimer functionalized with oligo(phenylene vinylene) groups is used as a stabilizing agent in the fabrication of CdS nanoparticles. The solvent-dependent conformational behavior of this electroactive dendrimer is used to generate various organic-inorganic semiconductor composites. In chloroform solution, CdS spherical nanoparticles are formed, whereas in a chloroform/ methanol mixture (6:1, v/v) platelike structures evolve. At the air-water interface, nanoparticulate films with a leaf-nerve-like organization of nanoparticles are formed, whereas vesicles generated in aqueous media become overgrown with CdS.
引用
收藏
页码：2571 / 2576
页数：6
相关论文
共 24 条
[1]   Self-assembling peptidomimetic monolayer nucleates oriented CdS nanocrystals [J].
Bekele, H ;
Fendler, JH ;
Kelly, JW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (31) :7266-7267
[2]   Semiconducting superlattices templated by molecular assemblies [J].
Braun, PV ;
Osenar, P ;
Stupp, SI .
NATURE, 1996, 380 (6572) :325-328
[3]  
COLVIN VL, 1994, NATURE, V370, P354, DOI 10.1038/370354a0
[4]   Charge separation and transport in conjugated-polymer/semiconductor-nanocrystal composites studied by photoluminescence quenching and photoconductivity [J].
Greenham, NC ;
Peng, XG ;
Alivisatos, AP .
PHYSICAL REVIEW B, 1996, 54 (24) :17628-17637
[5]   Thioalkanoates as site-directing nucleating centers for the preparation of patterns of CdS nanoparticles within 3-D crystals and LB films of Cd alkanoates [J].
Guo, SW ;
Konopny, L ;
Popovitz-Biro, R ;
Cohen, H ;
Porteanu, H ;
Lifshitz, E ;
Lahav, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (41) :9589-9598
[6]  
Hanus LH, 2000, LANGMUIR, V16, P2621, DOI 10.1021/1a981505a
[7]   SMALL-PARTICLE RESEARCH - PHYSICOCHEMICAL PROPERTIES OF EXTREMELY SMALL COLLOIDAL METAL AND SEMICONDUCTOR PARTICLES [J].
HENGLEIN, A .
CHEMICAL REVIEWS, 1989, 89 (08) :1861-1873
[8]  
HERRON N, 1989, J AM CHEM SOC, V11, P350
[9]   Polyamine-quantum dot nanocomposites: Linear versus starburst stabilizer architectures [J].
Huang, JM ;
Sooklal, K ;
Murphy, CJ ;
Ploehn, HJ .
CHEMISTRY OF MATERIALS, 1999, 11 (12) :3595-3601
[10]  
Kumar ND, 1997, APPL PHYS LETT, V71, P1388, DOI 10.1063/1.120196
123