Synthesis and characterization of the dodecahexaynediyldiiron complex, Fp*-(CC)6-Fp* [Fp*= Fe(η5-C5Me5)(CO)2], the longest structurally characterized polyynediyl complex

被引：94
作者：
Sakurai, A [1 ]
Akita, M [1 ]
Moro-oka, Y [1 ]
机构：
[1] Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
来源：
ORGANOMETALLICS | 1999年 / 18卷 / 16期
关键词：
D O I：
10.1021/om990266i
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Cu-catalyzed oxidative coupling of the hexatriynyl complex Fp*-(C=C)(3)-H affords the dodecahexynediyl diiron complex Fp*-(C=C)(6)-Fp*. Its linear but slightly twisted structure has been revealed by X-ray crystallography.
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页码：3241 / 3244
页数：4
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