Effect of multi-walled carbon nanotubes on the stability of dye sensitized solar cells

被引:60
作者
Dembele, K. T. [1 ,2 ,3 ]
Nechache, R. [1 ,2 ,3 ]
Nikolova, L. [1 ]
Vomiero, A. [4 ]
Santato, C. [5 ]
Licoccia, S. [2 ,3 ]
Rosei, F. [1 ,6 ]
机构
[1] INRS EMT, Varennes, PQ J3X 1S2, Canada
[2] Univ Roma Tor Vergata, Dept Chem Sci & Technol, I-00133 Rome, Italy
[3] Univ Roma Tor Vergata, NAST Ctr, I-00133 Rome, Italy
[4] CNR, Ist Acust & Sensorist Orso Mario Corbino, Lab SENSOR, I-25123 Brescia, Italy
[5] Ecole Polytech Montreal, Dept Genie Phys, Montreal, PQ H3T 1J4, Canada
[6] McGill Univ, Ctr Self Assembled Chem Struct, Montreal, PQ H3A 2K6, Canada
基金
加拿大自然科学与工程研究理事会; 加拿大创新基金会;
关键词
Dye sensitized solar cells (DSSCs); Multi-walled carbon nanotubes (MWCNTs); Power conversion efficiency; Titanium dioxide; DSSC operational stability; PHOTOVOLTAIC PERFORMANCE; ELECTRON-TRANSPORT; COUNTER ELECTRODES; TIO2; FILMS; EFFICIENCY; FABRICATION; IMPROVEMENT; MECHANISMS; ARRAYS;
D O I
10.1016/j.jpowsour.2013.01.075
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report the improvement of the operational stability of dye-sensitized solar cells (DSSCs) by incorporating multi-wall carbon nanotubes (MWCNTs) in conventional nanostructured semiconducting TiO2 photoanodes. DSSCs were prepared by adding various concentrations of MWCNTs (up to 1.0% wt.) to TiO2 anatase nanoparticles. Optimization of MWCNT concentration leads to photoconversion efficiency as high as 4.1% as opposed to 3.7% for pure TiO2 photoanodes. The performance of the solar cells was measured for 10 consecutive days of continuous ambient light exposure. MWCNT addition results in the decrease of efficiency from 4.1% to 3.7%, while a decrease from 3.7% to 2.4% was recorded in pure TiO2 photoanodes. These results are encouraging toward the commercial exploitation of DSSCs. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:93 / 97
页数:5
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