Visible-light photoactivity of hierarchical porous carbon supported N-doped TiO2

被引:7
作者
Huang, D. [1 ]
Liu, Q. [1 ]
Miyamoto, Y. [2 ]
Matsumoto, T. [3 ]
Tojo, T. [3 ]
Ding, J. [1 ]
Zhang, D. [1 ]
机构
[1] Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
[2] Osaka Univ, Joining & Welding Res Inst, Osaka 5670047, Japan
[3] Toyo Tanso Co Ltd, Adv Carbon Technol Ctr, Osaka 5550011, Japan
基金
中国国家自然科学基金;
关键词
Nitrogen-doped TiO2; Hierarchical porous carbons; Auger electronic spectrometer; Bandgap; Photocatalysis; REMOTE PHOTOCATALYTIC OXIDATION; TITANIUM-DIOXIDE; NITROGEN; SURFACE; CHEMISORPTION; PARTICLES; ANATASE; ALLOY; FILMS; WATER;
D O I
10.1007/s10934-011-9561-y
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Hierarchical porous carbon fabricated from biomass provides an effective support for catalysts. Nitrogen doped TiO2 particles (50 nm in size) synthesized from titanium tetraethoxide were loaded uniformly on the porous carbons carbonized from Zizania latifolia leaves by a sol-gel method. X-Ray diffraction and Auger Electronic Spectrometer analysis indicated that nitrogen atoms were doped into anatase TiO2 lattices. The bandgap of the nitrogen doped TiO2 derived from the light absorption spectrum was about 3.05 eV. The nitrogen doped TiO2 on the hierarchical porous carbon hybrid photocatalysts showed a high degradation rate of 2-propanol in water with visible light irradiation.
引用
收藏
页码:1003 / 1008
页数:6
相关论文
共 34 条
[1]   Solution-phase grafting of titanium dioxide onto the pore surface of mesoporous silicates: Synthesis and structural characterization [J].
Aronson, BJ ;
Blanford, CF ;
Stein, A .
CHEMISTRY OF MATERIALS, 1997, 9 (12) :2842-2851
[2]   Characterization of N-doped TiO2 films prepared by reactive sputtering using air/Ar mixtures [J].
Chan, Mu-Hsuan ;
Lu, Fu-Hsing .
THIN SOLID FILMS, 2009, 518 (05) :1369-1372
[3]   leMacroporous conducting matrix: Fabrication and application as electrocatalyst support [J].
Chen, Shao Xiang ;
Zhang, Xin ;
Shen, Pei Kang .
ELECTROCHEMISTRY COMMUNICATIONS, 2006, 8 (05) :713-719
[4]   Doped semiconductor nanomaterials [J].
Chen, XB ;
Lou, YB ;
Dayal, S ;
Qiu, XF ;
Krolicki, R ;
Burda, C ;
Zhao, CF ;
Becker, J .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2005, 5 (09) :1408-1420
[5]   Photocatalytic TiO2 on copper alloy for antimicrobial purposes [J].
Chung, Chi-Jen ;
Chiang, Chung-Chien ;
Chen, Chang-Hsiung ;
Hsiao, Ching-Hung ;
Lin, Hsin-I ;
Hsieh, Ping-Yen ;
He, Ju-Liang .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2008, 85 (1-2) :103-108
[6]   HETEROGENEOUS PHOTOCATALYTIC OXIDATION OF CYANIDE AND SULFITE IN AQUEOUS-SOLUTIONS AT SEMICONDUCTOR POWDERS [J].
FRANK, SN ;
BARD, AJ .
JOURNAL OF PHYSICAL CHEMISTRY, 1977, 81 (15) :1484-1488
[7]   ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].
FUJISHIMA, A ;
HONDA, K .
NATURE, 1972, 238 (5358) :37-+
[8]   A promoting effect of NH4F addition on the photocatalytic activity of sol-gel TiO2 films [J].
Hattori, A ;
Yamamoto, M ;
Tada, H ;
Ito, S .
CHEMISTRY LETTERS, 1998, (08) :707-708
[9]   Preparation and characterization of high-surface-area TiO2/activated carbon by low-temperature impregnation [J].
Huang, D. ;
Miyamoto, Y. ;
Matsumoto, T. ;
Tojo, T. ;
Fan, T. ;
Ding, J. ;
Guo, Q. ;
Zhang, D. .
SEPARATION AND PURIFICATION TECHNOLOGY, 2011, 78 (01) :9-15
[10]   Photocatalytic remote oxidation with various photocatalysts and enhancement of its activity [J].
Kubo, W ;
Tatsuma, T .
JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (30) :3104-3108