Enhanced Piezoelectric Properties of (Ba1-xCax)(Ti0.92Sn0.08)O3 Lead-Free Ceramics

被引：125

作者：

Zhu, Li-Feng ^{[1
]}

Zhang, Bo-Ping ^{[1
]}

Zhao, Xiao-Kun ^{[1
]}

Zhao, Lei ^{[1
]}

Zhou, Peng-Fei ^{[1
]}

Li, Jing-Feng ^{[2
]}

机构：

[1] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China

[2] Tsinghua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 2013年 / 96卷 / 01期

关键词：

FREE PIEZOCERAMICS; THIN-FILMS;

D O I：

10.1111/jace.12038

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

(Ba1-xCax)(Ti0.92Sn0.08)O3 (x=0.000.06mol) ceramics with a high relative density over 96% were prepared by a conventional sintering method at 1480 degrees C. At room temperature, a polymorphic phase transition from orthorhombic phase to tetragonal phase was confirmed by the XRD patterns in the composition range of 0.04=x=0.06. A high piezoelectric coefficient d33 up to 568pC/N was obtained at x=0.05mol, which is higher than the other component of (Ba,Ca)(Ti,Sn)O3 system. At the same time, the corresponding planar electromechanical coupling factor kp, converse piezoelectric coefficient dS/dE, and dielectric constant er reach 47.7%, 1013pm/V, and 23000, respectively. These results indicate that the (Ba,Ca)(Ti,Sn)O3 ceramics are a promising candidate to replace for the lead-based piezoelectric materials.

引用

页码：241 / 245

页数：5

共 24 条

[1] Contributions to the piezoelectric effect in ferroelectric single crystals and ceramics [J].

Damjanovic, D .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2005, 88 (10) :2663-2676

[2] Ferroelectric, dielectric and piezoelectric properties of ferroelectric thin films and ceramics [J].

Damjanovic, D .

REPORTS ON PROGRESS IN PHYSICS, 1998, 61 (09) :1267-1324

[3] Phase coexistence and ferroelastic texture in high strain (1-x)Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3 piezoceramics [J].

Ehmke, Matthias C. ;

Ehrlich, Steven N. ;

Blendell, John E. ;

Bowman, Keith J. .

JOURNAL OF APPLIED PHYSICS, 2012, 111 (12)

[4] Polarization rotation mechanism for ultrahigh electromechanical response in single-crystal piezoelectrics [J].

Fu, HX ;

Cohen, RE .

NATURE, 2000, 403 (6767) :281-283

[5] DIFFUSE FERROELECTRIC PHASE-TRANSITIONS IN BA(TI1-YZRY)O3 CERAMICS [J].

HENNINGS, D ;

SCHNELL, A ;

SIMON, G .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1982, 65 (11) :539-544

[6] Large Piezoelectric Coefficient in (Ba1-xCax)(Ti0.96Sn0.04)O3 Lead-Free Ceramics [J].

Li, Wei ;

Xu, Zhijun ;

Chu, Ruiqing ;

Fu, Peng ;

Zang, Guozhong .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2011, 94 (12) :4131-4133

[7] Enhanced ferroelectric properties in (Ba1-xCax)(Ti0.94Sn0.06)O3 lead-free ceramics [J].

Li, Wei ;

Xu, Zhijun ;

Chu, Ruiqing ;

Fu, Peng ;

Zang, Guozhong .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2012, 32 (03) :517-520

[8] Large Piezoelectric Effect in Pb-Free Ceramics [J].

Liu, Wenfeng ;

Ren, Xiaobing .

PHYSICAL REVIEW LETTERS, 2009, 103 (25)

[9] Phase structure and nano-domain in high performance of BaTiO3 piezoelectric ceramics [J].

Ma, Nan ;

Zhang, Bo-Ping ;

Yang, Wei-Gang ;

Guo, Dong .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2012, 32 (05) :1059-1066

[10] Review: environmental friendly lead-free piezoelectric materials [J].

Panda, P. K. .

JOURNAL OF MATERIALS SCIENCE, 2009, 44 (19) :5049-5062

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