Developments in the Aerobic Oxidation of Amines

被引：248
作者：
Schuemperli, Martin T. [1 ]
Hammond, Ceri [1 ]
Hermans, Ive [1 ]
机构：
[1] Swiss Fed Inst Technol, Dept Chem & Appl Biosci, CH-8093 Zurich, Switzerland
来源：
ACS CATALYSIS | 2012年 / 2卷 / 06期
关键词：
gold catalysis; sustainable chemistry; oxidative dehydrogenation; oximes; imines; SUPPORTED GOLD NANOPARTICLES; PRIMARY ALIPHATIC-AMINES; AROMATIC AZO-COMPOUNDS; SELECTIVE OXIDATION; RUTHENIUM HYDROXIDE; MOLECULAR-OXYGEN; CATALYTIC-OXIDATION; EFFICIENT CATALYST; HYDROGEN-PEROXIDE; SECONDARY-AMINES;
D O I：
10.1021/cs300212q
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The oxidative upgrading of amines offers great opportunities for the sustainable production of key N-containing building-blocks for the modern chemical industry. Compared to other oxyfunctionalizations, and despite their potential, amine oxidation reactions are barely explored in the literature. This review aims at drawing attention to this important area and highlights both the major achievements and the challenges that still remain.
引用
收藏
页码：1108 / 1117
页数：10
相关论文
共 100 条
  • [1] A collaborative effect between gold and a support induces the selective oxidation of alcohols
    Abad, A
    Concepción, P
    Corma, A
    García, H
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (26) : 4066 - 4069
  • [2] Catalyst parameters determining activity and selectivity of supported gold nanoparticles for the aerobic oxidation of alcohols:: The molecular reaction mechanism
    Abad, Alberto
    Corma, Avelino
    Garcia, Hermenegildo
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (01) : 212 - 222
  • [3] The catalytic activity of a cyclometalated ruthenium(III) complex for aerobic oxidative dehydrogenation of benzylamines
    Aiki, Shota
    Taketoshi, Ayako
    Kuwabara, Junpei
    Koizumi, Take-aki
    Kanbara, Takaki
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (06) : 1301 - 1304
  • [4] [Anonymous], 2007, GREEN CHEM CATALYSIS
  • [5] Armor J. N., 1982, U.S. Patent 4504681, Patent No. 4504681
  • [6] THE SELECTIVE OXIDATION OF CYCLOHEXYLAMINE TO ITS OXIME
    ARMOR, JN
    CARLSON, EJ
    RIGGITANO, R
    YAMANIS, J
    ZAMBRI, PM
    [J]. JOURNAL OF CATALYSIS, 1983, 83 (02) : 487 - 490
  • [7] Development of a New Generation of Gold Catalysts for Amine Oxidation
    Aschwanden, Linda
    Mallat, Tamas
    Maciejewski, Marek
    Krumeich, Frank
    Baiker, Alfons
    [J]. CHEMCATCHEM, 2010, 2 (06) : 666 - 673
  • [8] Magnetically Separable Gold Catalyst for the Aerobic Oxidation of Amines
    Aschwanden, Linda
    Panella, Barbara
    Rossbach, Peggy
    Keller, Beat
    Baiker, Alfons
    [J]. CHEMCATCHEM, 2009, 1 (01) : 111 - 115
  • [9] A simple preparation of an efficient heterogeneous gold catalyst for aerobic amine oxidation
    Aschwanden, Linda
    Mallat, Tamas
    Krumeich, Frank
    Baiker, Alfons
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 309 (1-2) : 57 - 62
  • [10] Gold-catalyzed aerobic oxidation of dibenzylamine: Homogeneous or heterogeneous catalysis?
    Aschwanden, Linda
    Mallat, Tamas
    Grunwaldt, Jan-Dierk
    Krumeich, Frank
    Baiker, Alfons
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 300 (1-2) : 111 - 115
12345678910