ortho-Quinone Methides in Natural Product Synthesis

被引：348
作者：
Willis, Nicky J. [1 ]
Bray, Christopher D. [1 ]
机构：
[1] Queen Mary Univ London, Sch Biol & Chem Sci, London E1 4NS, England
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 30期
基金：
英国工程与自然科学研究理事会;
关键词：
benzopyran; cycloaddition; electrocyclic reactions; natural products; ortho-quinone methide; DIELS-ALDER REACTIONS; ENANTIOSELECTIVE TOTAL-SYNTHESIS; ONE-POT SYNTHESIS; BIOMIMETIC SYNTHESIS; FORMAL SYNTHESIS; CONCISE SYNTHESIS; BERKELIC ACID; ROBUSTADIAL-A; GENERATION; CYCLIZATION;
D O I：
10.1002/chem.201200619
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
ortho-Quinone methides (o-QMs) are emerging as highly useful intermediates, the inherent reactivity of which can be used in linchpin reactions for the construction of complex natural products. This review encompasses the major contributions in this field, exemplifying the major strategies and reactivity modes which can be applied.
引用
收藏
页码：9160 / 9173
页数：14
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