Multi-scale study of CNT and CNT-COOH reinforced epoxy composites: dispersion state, interfacial interaction vs mechanical properties

被引：9
作者：
Yang, Haitang [1 ,2 ,3 ]
Yang, Yanping [1 ,2 ]
Liu, Yu [1 ,2 ]
He, Delong [4 ]
Bai, Jinbo [4 ]
机构：
[1] Cent South Univ, Sch Aeronaut & Astronaut, Changsha, Hunan, Peoples R China
[2] Cent South Univ, Hunan Key Lab Adv Fibers & Composites, Changsha, Hunan, Peoples R China
[3] Cent South Univ, State Key Lab High Performance Complex Mfg, Changsha, Hunan, Peoples R China
[4] Univ Paris Saclay, Cent Supelec, CNRS, UMR 8579,Lab Mecan Sols Struct & Mat MSSMat, Gif Sur Yvette, France
来源：
COMPOSITE INTERFACES | 2021年 / 28卷 / 04期
基金：
中国国家自然科学基金;
关键词：
CNTs; composite; interphase; EELS; mechanical property; WALLED CARBON NANOTUBES; NANOCOMPOSITES; PERFORMANCE; FABRICATION; INTERPHASE; FIBERS;
D O I：
10.1080/09276440.2020.1780556
中图分类号：
TB33 [复合材料];
学科分类号：
摘要：
A precise evaluation of the influence of the dispersion and interface on the mechanical properties is the foundation to fabricate high-performance composites. In this work, original CNTs and carboxylic acid-modified CNTs (CNT-COOH) were chosen as the models, and a multi-scale study of CNTs reinforced epoxy composites was conducted, including the mechanical property test, the dispersion state evaluation and the interface analysis. The interface analysis was conducted by combining scanning transmission electron microscopy (STEM) and electron energy-loss spectroscopy (EELS). A wider interphase region was successfully identified in the CNT-COOH/epoxy than in the CNTs/epoxy composites. In addition, improved dispersion state has been achieved in the CNT-COOH/epoxy composite, which leads to a better mechanical performance for the CNT-COOH/epoxy composite. The successful characterization in multi-scale paves the way for a better understanding of the structure-property relationships in composites.
引用
收藏
页码：381 / 393
页数：13
相关论文
共 43 条
  • [1] Analytical and experimental investigation on magnetorheological behavior of CoFe2O4-rGO-incorporated epoxy fluid composites
    Adak, Nitai Chandra
    Chhetri, Suman
    Murmu, Naresh Chandra
    Samanta, Pranab
    Kuila, Tapas
    [J]. ADVANCED COMPOSITES AND HYBRID MATERIALS, 2019, 2 (02) : 266 - 278
  • [2] Andrews R, 2002, MACROMOL MATER ENG, V287, P395, DOI 10.1002/1439-2054(20020601)287:6<395::AID-MAME395>3.0.CO
  • [3] 2-S
  • [4] Balkanski M., 2000, Materials Science and Engineering: B, V76, P241, DOI [DOI 10.1016/S0921-5107(00)00444-X, DOI 10.1016/50921-5107(00)00111]
  • [5] Polyethylene thermal oxidative stabilisation in carbon nanotubes based nanocomposites
    Bocchini, Sergio
    Frache, Alberto
    Camino, Giovanni
    Claes, Michael
    [J]. EUROPEAN POLYMER JOURNAL, 2007, 43 (08) : 3222 - 3235
  • [6] Cadek M., 2002, STRUCTURAL ELECT PRO, V633, P1
  • [7] Fabrication and characterization of polycarbonate/carbon nanotubes composites
    Chen, Li
    Pang, Xiu-Jiang
    Qu, Mei-Zhen
    Zhang, Qing-tang
    Wang, Bin
    Zhang, Bai-Lan
    Yu, Zuo-Long
    [J]. COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2006, 37 (09) : 1485 - 1489
  • [8] In-situ pyrolyzed polymethylsilsesquioxane multi-walled carbon nanotubes derived ceramic nanocomposites for electromagnetic wave absorption
    Chen, Lixin
    Zhao, Jia
    Wang, Lei
    Peng, Fei
    Liu, Hu
    Zhang, Jiaoxia
    Gu, Junwei
    Guo, Zhanhu
    [J]. CERAMICS INTERNATIONAL, 2019, 45 (09) : 11756 - 11764
  • [9] Geometric constraints in the growth of nanotube-templated polymer monolayers
    Coleman, JN
    Ferreira, MS
    [J]. APPLIED PHYSICS LETTERS, 2004, 84 (05) : 798 - 800
  • [10] Mechanics of the interface for carbon nanotube-polymer composites
    Desai, AV
    Haque, MA
    [J]. THIN-WALLED STRUCTURES, 2005, 43 (11) : 1787 - 1803
12345