Functionalized IRMOF-3 as efficient heterogeneous catalyst for the synthesis of cyclic carbonates

被引：133

作者：

Zhou, Xi ^{[1
,2
]}

Zhang, Yi ^{[1
]}

Yang, Xiangui ^{[1
]}

Zhao, Liangzhong ^{[2
]}

Wang, Gongying ^{[1
]}

机构：

[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China

[2] Shaoyang Univ, Dept Biol & Chem Engn, Shaoyang 422000, Hunan, Peoples R China

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2012年 / 361卷

关键词：

Cyclic carbonate; Heterogeneous catalyst; IRMOF-3; Carbon dioxide; METAL-ORGANIC FRAMEWORKS; IONIC LIQUID; DIOXIDE; CO2; CYCLOADDITION; EPOXIDES;

D O I：

10.1016/j.molcata.2012.04.008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Functionalized isoreticular metal-organic framework-3 (IRMOF-3) was developed as a novel heterogeneous catalyst for the solventless synthesis of cyclic carbonates without any co-catalyst. The results showed that functionalized IRMOF-3 performed excellent activity, selectivity and reusability. The effects of reaction temperature, pressure, and time on the yield of propylene carbonate were tested. And the reaction mechanism was also discussed. (c) 2012 Published by Elsevier B.V.

引用

页码：12 / 16

页数：5

共 39 条

[21] The synthesis of organic carbonates from carbon dioxide [J].

Sakakura, Toshiyasu ;

Kohno, Kazufumi .

CHEMICAL COMMUNICATIONS, 2009, (11) :1312-1330

[22] Organic carbonates [J].

Shaikh, AAG ;

Sivaram, S .

CHEMICAL REVIEWS, 1996, 96 (03) :951-976

[23]

Shimada S., 2009, CHEM COMMUN, P1136

[24] MOF-5/n-Bu4NBr: an efficient catalyst system for the synthesis of cyclic carbonates from epoxides and CO2 under mild conditions [J].

Song, Jinliang ;

Zhang, Zhaofu ;

Hu, Suqin ;

Wu, Tianbin ;

Jiang, Tao ;

Han, Buxing .

GREEN CHEMISTRY, 2009, 11 (07) :1031-1036

[25] Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites [J].

Stock, Norbert ;

Biswas, Shyam .

CHEMICAL REVIEWS, 2012, 112 (02) :933-969

[26] Hydroxyl-functionalized ionic liquid:: a novel efficient catalyst for chemical fixation of CO2 to cyclic carbonate [J].

Sun, Jian ;

Zhang, Suojiang ;

Cheng, Weiguo ;

Ren, Junyi .

TETRAHEDRON LETTERS, 2008, 49 (22) :3588-3591

[27] ZnCl2/phosphonium halide:: An efficient Lewis acid/base catalyst for the synthesis of cyclic carbonate [J].

Sun, Jian ;

Wang, Lei ;

Zhang, Suojiang ;

Li, Zengxi ;

Zhang, Xiangping ;

Dai, Wenbin ;

Mori, Ryohei .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 256 (1-2) :295-300

[28] Water as an efficient medium for the synthesis of cyclic carbonate [J].

Sun, Jian ;

Ren, Junyi ;

Zhang, Suojiang ;

Cheng, Weiguo .

TETRAHEDRON LETTERS, 2009, 50 (04) :423-426

[29] Cycloaddition of CO2 to epoxides over solid base catalysts [J].

Tu, M ;

Davis, RJ .

JOURNAL OF CATALYSIS, 2001, 199 (01) :85-91

[30] Immobilized ionic liquid/zinc chloride: Heterogeneous catalyst for synthesis of cyclic carbonates from carbon dioxide and epoxides [J].

Xiao, Lin-Fei ;

Li, Fu-Wei ;

Peng, Ha-Han ;

Xia, Chun-Gu .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 253 (1-2) :265-269

← 1 2 3 4 →