Functionalized IRMOF-3 as efficient heterogeneous catalyst for the synthesis of cyclic carbonates

被引：133

作者：

Zhou, Xi ^{[1
,2
]}

Zhang, Yi ^{[1
]}

Yang, Xiangui ^{[1
]}

Zhao, Liangzhong ^{[2
]}

Wang, Gongying ^{[1
]}

机构：

[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China

[2] Shaoyang Univ, Dept Biol & Chem Engn, Shaoyang 422000, Hunan, Peoples R China

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2012年 / 361卷

关键词：

Cyclic carbonate; Heterogeneous catalyst; IRMOF-3; Carbon dioxide; METAL-ORGANIC FRAMEWORKS; IONIC LIQUID; DIOXIDE; CO2; CYCLOADDITION; EPOXIDES;

D O I：

10.1016/j.molcata.2012.04.008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Functionalized isoreticular metal-organic framework-3 (IRMOF-3) was developed as a novel heterogeneous catalyst for the solventless synthesis of cyclic carbonates without any co-catalyst. The results showed that functionalized IRMOF-3 performed excellent activity, selectivity and reusability. The effects of reaction temperature, pressure, and time on the yield of propylene carbonate were tested. And the reaction mechanism was also discussed. (c) 2012 Published by Elsevier B.V.

引用

页码：12 / 16

页数：5

共 39 条

[1] Engineering Metal Organic Frameworks for Heterogeneous Catalysis [J].

Corma, A. ;

Garcia, H. ;

Llabres i Xamena, F. X. L. I. .

CHEMICAL REVIEWS, 2010, 110 (08) :4606-4655

[2] High-Efficiency Synthesis of Cyclic Carbonates from Epoxides and CO2 over Hydroxyl Ionic Liquid Catalyst Grafted onto Cross-Linked Polymer [J].

Dai, Wei-Li ;

Chen, Lang ;

Yin, Shuang-Feng ;

Li, Wen-Hua ;

Zhang, Yuan-Yuan ;

Luo, Sheng-Lian ;

Au, Chak-Tong .

CATALYSIS LETTERS, 2010, 137 (1-2) :74-80

[3] Efficient carbonate synthesis under mild conditions through cycloaddition of carbon dioxide to oxiranes using a Zn(salphen) catalyst [J].

Decortes, Antonello ;

Martinez Belmonte, Marta ;

Benet-Buchholz, Jordi ;

Kleij, Arjan W. .

CHEMICAL COMMUNICATIONS, 2010, 46 (25) :4580-4582

[4] Synthesis of Styrene Carbonate from Carbon Dioxide and Styrene Oxide with Various Zinc Halide-Based Ionic Liquids [J].

Fujita, Shin-ichiro ;

Nishiura, Masahiro ;

Arai, Masahiko .

CATALYSIS LETTERS, 2010, 135 (3-4) :263-268

[5] Chemical fixation of carbon dioxide by NaI/PPh3/PhOH [J].

Huang, JW ;

Shi, M .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (17) :6705-6709

[6] Synthesis, morphology control, and properties of porous metal-organic coordination polymers [J].

Huang, LM ;

Wang, HT ;

Chen, JX ;

Wang, ZB ;

Sun, JY ;

Zhao, DY ;

Yan, YS .

MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 58 (02) :105-114

[7] Impact of preparation and handling on the hydrogen storage properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5) [J].

Kaye, Steven S. ;

Dailly, Anne ;

Yaghi, Omar M. ;

Long, Jeffrey R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (46) :14176-+

[8] Well-defined highly active heterogeneous catalyst system for the coupling reactions of carbon dioxide and epoxides [J].

Kim, HS ;

Kim, JJ ;

Kwon, HN ;

Chung, MJ ;

Lee, BG ;

Jang, HG .

JOURNAL OF CATALYSIS, 2002, 205 (01) :226-229

[9] Mixed-Linker Metal-Organic Frameworks as Catalysts for the Synthesis of Propylene Carbonate from Propylene Oxide and CO2 [J].

Kleist, Wolfgang ;

Jutz, Fabian ;

Maciejewski, Marek ;

Baiker, Alfons .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (24) :3552-3561

[10] Magnetic metal-organic frameworks [J].

Kurmoo, Mohamedally .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1353-1379

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